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Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)]
In the title compound, [Co(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), the two Co(II) atoms are both five-coordinated by four carboxylate O atoms, derived from two different cyclohexane-1,4-dicarboxylate (chdc) ligands, and an N atom, derived from one end of a 1,4-bis(imidazol-1-ylmethyl)benzene...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970306/ https://www.ncbi.nlm.nih.gov/pubmed/21577703 http://dx.doi.org/10.1107/S160053680903428X |
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author | Yu, Qun-Di Sun, Da-Jun Tiekink, Edward R. T. |
author_facet | Yu, Qun-Di Sun, Da-Jun Tiekink, Edward R. T. |
author_sort | Yu, Qun-Di |
collection | PubMed |
description | In the title compound, [Co(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), the two Co(II) atoms are both five-coordinated by four carboxylate O atoms, derived from two different cyclohexane-1,4-dicarboxylate (chdc) ligands, and an N atom, derived from one end of a 1,4-bis(imidazol-1-ylmethyl)benzene molecule (1,4-bix), in a distorted square-pyramidal environment. Each end of the chdc ligand links pairs of Co(II) atoms into a paddle-wheel assembly, i.e. Co(2)(O(2)CR′)(4); these are connected into rows because of the bridging nature of the chdc ligands, and the rows are further connected into a two-dimensional layer through the 1,4-bix ligands. The 1,4-bix ligand, which is disposed about a centre of inversion, is disorderd. Two positions were discerned for the –CH(2)(C(6)H(4))CH(2)– residue, with the major component having a site-occupancy factor of 0.512 (9). |
format | Text |
id | pubmed-2970306 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29703062010-12-30 Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)] Yu, Qun-Di Sun, Da-Jun Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), the two Co(II) atoms are both five-coordinated by four carboxylate O atoms, derived from two different cyclohexane-1,4-dicarboxylate (chdc) ligands, and an N atom, derived from one end of a 1,4-bis(imidazol-1-ylmethyl)benzene molecule (1,4-bix), in a distorted square-pyramidal environment. Each end of the chdc ligand links pairs of Co(II) atoms into a paddle-wheel assembly, i.e. Co(2)(O(2)CR′)(4); these are connected into rows because of the bridging nature of the chdc ligands, and the rows are further connected into a two-dimensional layer through the 1,4-bix ligands. The 1,4-bix ligand, which is disposed about a centre of inversion, is disorderd. Two positions were discerned for the –CH(2)(C(6)H(4))CH(2)– residue, with the major component having a site-occupancy factor of 0.512 (9). International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970306/ /pubmed/21577703 http://dx.doi.org/10.1107/S160053680903428X Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yu, Qun-Di Sun, Da-Jun Tiekink, Edward R. T. Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)] |
title | Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)] |
title_full | Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)] |
title_fullStr | Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)] |
title_full_unstemmed | Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)] |
title_short | Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(II)] |
title_sort | poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dicobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970306/ https://www.ncbi.nlm.nih.gov/pubmed/21577703 http://dx.doi.org/10.1107/S160053680903428X |
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