Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone

The title compound, C(25)H(22)O(5), was obtained by a dehydrogenative carbonyl­ation reaction. It crystallizes with one half-mol­ecule in the asymmetric unit. The mol­ecules have crystallographic C (2) symmetry and the two atoms of the carbonyl group are located on the rotation axis. The meth­oxy gr...

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Detalles Bibliográficos
Autores principales: Bolte, Michael, Schwarz, Lothar, Hashmi, A. Stephen K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970307/
https://www.ncbi.nlm.nih.gov/pubmed/21577796
http://dx.doi.org/10.1107/S1600536809034333
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author Bolte, Michael
Schwarz, Lothar
Hashmi, A. Stephen K.
author_facet Bolte, Michael
Schwarz, Lothar
Hashmi, A. Stephen K.
author_sort Bolte, Michael
collection PubMed
description The title compound, C(25)H(22)O(5), was obtained by a dehydrogenative carbonyl­ation reaction. It crystallizes with one half-mol­ecule in the asymmetric unit. The mol­ecules have crystallographic C (2) symmetry and the two atoms of the carbonyl group are located on the rotation axis. The meth­oxy groups are coplanar with the benzene ring to which they are attached [C—C—O—C = 1.0 (6)°]. The two furan rings are inclined at 17.3 (3)° with respect to each other and the dihedral angle between the furan ring and the benzene ring is 75.83 (12)°. The crystal structure is stabilized by C—H⋯O hydrogen bonds.
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spelling pubmed-29703072010-12-30 Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone Bolte, Michael Schwarz, Lothar Hashmi, A. Stephen K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(22)O(5), was obtained by a dehydrogenative carbonyl­ation reaction. It crystallizes with one half-mol­ecule in the asymmetric unit. The mol­ecules have crystallographic C (2) symmetry and the two atoms of the carbonyl group are located on the rotation axis. The meth­oxy groups are coplanar with the benzene ring to which they are attached [C—C—O—C = 1.0 (6)°]. The two furan rings are inclined at 17.3 (3)° with respect to each other and the dihedral angle between the furan ring and the benzene ring is 75.83 (12)°. The crystal structure is stabilized by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970307/ /pubmed/21577796 http://dx.doi.org/10.1107/S1600536809034333 Text en © Bolte et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bolte, Michael
Schwarz, Lothar
Hashmi, A. Stephen K.
Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone
title Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone
title_full Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone
title_fullStr Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone
title_full_unstemmed Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone
title_short Bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone
title_sort bis[5-(4-methoxy­benz­yl)furan-3-yl]methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970307/
https://www.ncbi.nlm.nih.gov/pubmed/21577796
http://dx.doi.org/10.1107/S1600536809034333
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AT schwarzlothar bis54methoxybenzylfuran3ylmethanone
AT hashmiastephenk bis54methoxybenzylfuran3ylmethanone

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