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Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate

In the title complex, [Co(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Co(II) ion is coordinated by two sets of two N atoms and an O atom from two independent tridendate ligands in a distorted octa­hedral coordination environment. There are significant differences between chemically eq...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Yun, Ruirui, Sun, Tao, Li, Ke, Meng, Xuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970309/
https://www.ncbi.nlm.nih.gov/pubmed/21577726
http://dx.doi.org/10.1107/S1600536809035934
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author Wu, Huilu
Yun, Ruirui
Sun, Tao
Li, Ke
Meng, Xuan
author_facet Wu, Huilu
Yun, Ruirui
Sun, Tao
Li, Ke
Meng, Xuan
author_sort Wu, Huilu
collection PubMed
description In the title complex, [Co(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Co(II) ion is coordinated by two sets of two N atoms and an O atom from two independent tridendate ligands in a distorted octa­hedral coordination environment. There are significant differences between chemically equivalent coordination bond lengths. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds and weak π–π stacking inter­actions [centroid–centroid distance 3.495 (1) Å]. In one of the anions one nitro group is rotationally disordered about the C—N bond with refined occupancies of 0.524 (8) and 0.476 (8).
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spelling pubmed-29703092010-12-30 Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate Wu, Huilu Yun, Ruirui Sun, Tao Li, Ke Meng, Xuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Co(II) ion is coordinated by two sets of two N atoms and an O atom from two independent tridendate ligands in a distorted octa­hedral coordination environment. There are significant differences between chemically equivalent coordination bond lengths. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds and weak π–π stacking inter­actions [centroid–centroid distance 3.495 (1) Å]. In one of the anions one nitro group is rotationally disordered about the C—N bond with refined occupancies of 0.524 (8) and 0.476 (8). International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970309/ /pubmed/21577726 http://dx.doi.org/10.1107/S1600536809035934 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Huilu
Yun, Ruirui
Sun, Tao
Li, Ke
Meng, Xuan
Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate
title Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate
title_full Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate
title_fullStr Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate
title_full_unstemmed Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate
title_short Bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(II) dipicrate dimethyl­formamide disolvate
title_sort bis[bis­(1-ethyl­benzimidazol-2-ylmeth­yl) ether]cobalt(ii) dipicrate dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970309/
https://www.ncbi.nlm.nih.gov/pubmed/21577726
http://dx.doi.org/10.1107/S1600536809035934
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