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Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate
In the title complex, [Co(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Co(II) ion is coordinated by two sets of two N atoms and an O atom from two independent tridendate ligands in a distorted octahedral coordination environment. There are significant differences between chemically eq...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970309/ https://www.ncbi.nlm.nih.gov/pubmed/21577726 http://dx.doi.org/10.1107/S1600536809035934 |
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author | Wu, Huilu Yun, Ruirui Sun, Tao Li, Ke Meng, Xuan |
author_facet | Wu, Huilu Yun, Ruirui Sun, Tao Li, Ke Meng, Xuan |
author_sort | Wu, Huilu |
collection | PubMed |
description | In the title complex, [Co(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Co(II) ion is coordinated by two sets of two N atoms and an O atom from two independent tridendate ligands in a distorted octahedral coordination environment. There are significant differences between chemically equivalent coordination bond lengths. The crystal structure is stabilized by weak intermolecular C—H⋯O hydrogen bonds and weak π–π stacking interactions [centroid–centroid distance 3.495 (1) Å]. In one of the anions one nitro group is rotationally disordered about the C—N bond with refined occupancies of 0.524 (8) and 0.476 (8). |
format | Text |
id | pubmed-2970309 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29703092010-12-30 Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate Wu, Huilu Yun, Ruirui Sun, Tao Li, Ke Meng, Xuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(20)H(22)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Co(II) ion is coordinated by two sets of two N atoms and an O atom from two independent tridendate ligands in a distorted octahedral coordination environment. There are significant differences between chemically equivalent coordination bond lengths. The crystal structure is stabilized by weak intermolecular C—H⋯O hydrogen bonds and weak π–π stacking interactions [centroid–centroid distance 3.495 (1) Å]. In one of the anions one nitro group is rotationally disordered about the C—N bond with refined occupancies of 0.524 (8) and 0.476 (8). International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970309/ /pubmed/21577726 http://dx.doi.org/10.1107/S1600536809035934 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Huilu Yun, Ruirui Sun, Tao Li, Ke Meng, Xuan Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate |
title | Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate |
title_full | Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate |
title_fullStr | Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate |
title_full_unstemmed | Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate |
title_short | Bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(II) dipicrate dimethylformamide disolvate |
title_sort | bis[bis(1-ethylbenzimidazol-2-ylmethyl) ether]cobalt(ii) dipicrate dimethylformamide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970309/ https://www.ncbi.nlm.nih.gov/pubmed/21577726 http://dx.doi.org/10.1107/S1600536809035934 |
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