(Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate

In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol­ecule in the asymmetric unit. Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride...

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Detalles Bibliográficos
Autores principales: Ravichandran, K., Ramesh, P., Tamilselvan, M., Anbalagan, K., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970310/
https://www.ncbi.nlm.nih.gov/pubmed/21577710
http://dx.doi.org/10.1107/S1600536809034849
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author Ravichandran, K.
Ramesh, P.
Tamilselvan, M.
Anbalagan, K.
Ponnuswamy, M. N.
author_facet Ravichandran, K.
Ramesh, P.
Tamilselvan, M.
Anbalagan, K.
Ponnuswamy, M. N.
author_sort Ravichandran, K.
collection PubMed
description In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol­ecule in the asymmetric unit. Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride ion. The crystal packing is through N—H⋯O, N—H⋯Cl and O—H⋯Cl inter­actions.
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spelling pubmed-29703102010-12-30 (Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate Ravichandran, K. Ramesh, P. Tamilselvan, M. Anbalagan, K. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(C(2)H(8)N(2))(2)(C(7)H(9)N)]Cl(2)·0.5H(2)O, there are two crystallographically independent cations and anions and one water mol­ecule in the asymmetric unit. Both Co(III) ions are bonded to two chelating ethylenediamine ligands, one benzylamine molecule and one chloride ion. The crystal packing is through N—H⋯O, N—H⋯Cl and O—H⋯Cl inter­actions. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970310/ /pubmed/21577710 http://dx.doi.org/10.1107/S1600536809034849 Text en © Ravichandran et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ravichandran, K.
Ramesh, P.
Tamilselvan, M.
Anbalagan, K.
Ponnuswamy, M. N.
(Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate
title (Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate
title_full (Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate
title_fullStr (Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate
title_full_unstemmed (Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate
title_short (Benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(III) dichloride hemihydrate
title_sort (benzyl­amine)chloridobis(ethane-1,2-diamine)cobalt(iii) dichloride hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970310/
https://www.ncbi.nlm.nih.gov/pubmed/21577710
http://dx.doi.org/10.1107/S1600536809034849
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AT tamilselvanm benzylaminechloridobisethane12diaminecobaltiiidichloridehemihydrate
AT anbalagank benzylaminechloridobisethane12diaminecobaltiiidichloridehemihydrate
AT ponnuswamymn benzylaminechloridobisethane12diaminecobaltiiidichloridehemihydrate

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