2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride

The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter­action between the amino N and Te(II) atoms. The Te—C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te...

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Detalles Bibliográficos
Autores principales: Chakraborty, Tapash, Singh, Harkesh B., Butcher, Ray J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970312/
https://www.ncbi.nlm.nih.gov/pubmed/21578002
http://dx.doi.org/10.1107/S1600536809038161
Descripción
Sumario:The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter­action between the amino N and Te(II) atoms. The Te—C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te—C bond [2.1242 (18) Å] due to the hypervalent inter­action. The bond angle for the trans N—Te—C atoms [164.92 (6)°] deviates significantly from linearity.

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