2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride

The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter­action between the amino N and Te(II) atoms. The Te—C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te...

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Detalles Bibliográficos
Autores principales: Chakraborty, Tapash, Singh, Harkesh B., Butcher, Ray J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970312/
https://www.ncbi.nlm.nih.gov/pubmed/21578002
http://dx.doi.org/10.1107/S1600536809038161
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author Chakraborty, Tapash
Singh, Harkesh B.
Butcher, Ray J.
author_facet Chakraborty, Tapash
Singh, Harkesh B.
Butcher, Ray J.
author_sort Chakraborty, Tapash
collection PubMed
description The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter­action between the amino N and Te(II) atoms. The Te—C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te—C bond [2.1242 (18) Å] due to the hypervalent inter­action. The bond angle for the trans N—Te—C atoms [164.92 (6)°] deviates significantly from linearity.
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spelling pubmed-29703122010-12-30 2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride Chakraborty, Tapash Singh, Harkesh B. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(17)NTe, is a heteroleptic Te, N-bidentate ligand having a short Te⋯N contact [2.8079 (16) Å] involving a secondary bonding inter­action between the amino N and Te(II) atoms. The Te—C bond [2.136 (2) Å] trans to the amino group is slightly elongated compared to the other Te—C bond [2.1242 (18) Å] due to the hypervalent inter­action. The bond angle for the trans N—Te—C atoms [164.92 (6)°] deviates significantly from linearity. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970312/ /pubmed/21578002 http://dx.doi.org/10.1107/S1600536809038161 Text en © Chakraborty et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chakraborty, Tapash
Singh, Harkesh B.
Butcher, Ray J.
2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride
title 2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride
title_full 2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride
title_fullStr 2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride
title_full_unstemmed 2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride
title_short 2-(Dimethyl­amino­meth­yl)phenyl phenyl telluride
title_sort 2-(dimethyl­amino­meth­yl)phenyl phenyl telluride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970312/
https://www.ncbi.nlm.nih.gov/pubmed/21578002
http://dx.doi.org/10.1107/S1600536809038161
work_keys_str_mv AT chakrabortytapash 2dimethylaminomethylphenylphenyltelluride
AT singhharkeshb 2dimethylaminomethylphenylphenyltelluride
AT butcherrayj 2dimethylaminomethylphenylphenyltelluride

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