Cargando…
3-Benzyl-1-methylimidazolium picrate
In the title salt, C(11)H(13)N(2) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angles between the benzene ring in the cation and the imidazolium ring and the benzene ring of the picrate anion are 113.7 (2) and 116.3 (2)°, respectively. The imidazolium ring is nearly parallel to the benzene ring of the pic...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970314/ https://www.ncbi.nlm.nih.gov/pubmed/21577850 http://dx.doi.org/10.1107/S1600536809035454 |
Sumario: | In the title salt, C(11)H(13)N(2) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angles between the benzene ring in the cation and the imidazolium ring and the benzene ring of the picrate anion are 113.7 (2) and 116.3 (2)°, respectively. The imidazolium ring is nearly parallel to the benzene ring of the picrate anion, the dihedral angle between the planes being 2.6 (1)°. The nitro groups in the picrate anions are disordered (occupancy ratio 0.54:0.46). The crystal packing is stabilized by weak C—H⋯O interactions between the cation–anion pairs. |
---|