3-Benzyl-1-methyl­imidazolium picrate

In the title salt, C(11)H(13)N(2) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angles between the benzene ring in the cation and the imidazolium ring and the benzene ring of the picrate anion are 113.7 (2) and 116.3 (2)°, respectively. The imidazolium ring is nearly parallel to the benzene ring of the pic...

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Detalles Bibliográficos
Autores principales: Pi, Min, Liu, Xiu-Ling, Xu, Ji-Jun, Jin, Chuan-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970314/
https://www.ncbi.nlm.nih.gov/pubmed/21577850
http://dx.doi.org/10.1107/S1600536809035454
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author Pi, Min
Liu, Xiu-Ling
Xu, Ji-Jun
Jin, Chuan-Ming
author_facet Pi, Min
Liu, Xiu-Ling
Xu, Ji-Jun
Jin, Chuan-Ming
author_sort Pi, Min
collection PubMed
description In the title salt, C(11)H(13)N(2) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angles between the benzene ring in the cation and the imidazolium ring and the benzene ring of the picrate anion are 113.7 (2) and 116.3 (2)°, respectively. The imidazolium ring is nearly parallel to the benzene ring of the picrate anion, the dihedral angle between the planes being 2.6 (1)°. The nitro groups in the picrate anions are disordered (occupancy ratio 0.54:0.46). The crystal packing is stabilized by weak C—H⋯O inter­actions between the cation–anion pairs.
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spelling pubmed-29703142010-12-30 3-Benzyl-1-methyl­imidazolium picrate Pi, Min Liu, Xiu-Ling Xu, Ji-Jun Jin, Chuan-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(11)H(13)N(2) (+)·C(6)H(2)N(3)O(7) (−), the dihedral angles between the benzene ring in the cation and the imidazolium ring and the benzene ring of the picrate anion are 113.7 (2) and 116.3 (2)°, respectively. The imidazolium ring is nearly parallel to the benzene ring of the picrate anion, the dihedral angle between the planes being 2.6 (1)°. The nitro groups in the picrate anions are disordered (occupancy ratio 0.54:0.46). The crystal packing is stabilized by weak C—H⋯O inter­actions between the cation–anion pairs. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970314/ /pubmed/21577850 http://dx.doi.org/10.1107/S1600536809035454 Text en © Pi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pi, Min
Liu, Xiu-Ling
Xu, Ji-Jun
Jin, Chuan-Ming
3-Benzyl-1-methyl­imidazolium picrate
title 3-Benzyl-1-methyl­imidazolium picrate
title_full 3-Benzyl-1-methyl­imidazolium picrate
title_fullStr 3-Benzyl-1-methyl­imidazolium picrate
title_full_unstemmed 3-Benzyl-1-methyl­imidazolium picrate
title_short 3-Benzyl-1-methyl­imidazolium picrate
title_sort 3-benzyl-1-methyl­imidazolium picrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970314/
https://www.ncbi.nlm.nih.gov/pubmed/21577850
http://dx.doi.org/10.1107/S1600536809035454
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