Bis[4-oxido-2-oxo-2,3-di­hydro­pyrimidin-1-ium-5-carboxyl­ato(1.5−)-κ(2) O (4),O (5)]bis­(1,10-phenanthroline-κ(2) N,N′)dysprosium(III) dihydrate

In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-anti­prismatic geometry by two chelating 1,10-phenanthroline mol­ecules as well as two 4-oxido-2-oxo-2,3-di­hydro­pyrimidin-1-ium-5-carbox...

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Detalles Bibliográficos
Autores principales: Liu, Xianlin, Xing, Huihui, Miao, Jing, Jia, Maomao, Chen, Zilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970315/
https://www.ncbi.nlm.nih.gov/pubmed/21577746
http://dx.doi.org/10.1107/S1600536809036848
Descripción
Sumario:In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-anti­prismatic geometry by two chelating 1,10-phenanthroline mol­ecules as well as two 4-oxido-2-oxo-2,3-di­hydro­pyrimidin-1-ium-5-carboxyl­ato(1.5−) anions. N—H⋯O and O—H⋯O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N—H⋯N hydrogen bond is disordered around a twofold rotation axis.

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