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Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2) O (4),O (5)]bis(1,10-phenanthroline-κ(2) N,N′)dysprosium(III) dihydrate
In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-antiprismatic geometry by two chelating 1,10-phenanthroline molecules as well as two 4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carbox...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970315/ https://www.ncbi.nlm.nih.gov/pubmed/21577746 http://dx.doi.org/10.1107/S1600536809036848 |
| _version_ | 1782190410213359616 |
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| author | Liu, Xianlin Xing, Huihui Miao, Jing Jia, Maomao Chen, Zilu |
| author_facet | Liu, Xianlin Xing, Huihui Miao, Jing Jia, Maomao Chen, Zilu |
| author_sort | Liu, Xianlin |
| collection | PubMed |
| description | In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-antiprismatic geometry by two chelating 1,10-phenanthroline molecules as well as two 4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−) anions. N—H⋯O and O—H⋯O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N—H⋯N hydrogen bond is disordered around a twofold rotation axis. |
| format | Text |
| id | pubmed-2970315 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29703152010-12-30 Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2) O (4),O (5)]bis(1,10-phenanthroline-κ(2) N,N′)dysprosium(III) dihydrate Liu, Xianlin Xing, Huihui Miao, Jing Jia, Maomao Chen, Zilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Dy(C(5)H(2.5)N(2)O(4))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Dy(III) ion is located on a twofold rotation axis and is coordinated in a square-antiprismatic geometry by two chelating 1,10-phenanthroline molecules as well as two 4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−) anions. N—H⋯O and O—H⋯O hydrogen bonds help to stabilize the crystal structure. The H atom involved in an N—H⋯N hydrogen bond is disordered around a twofold rotation axis. International Union of Crystallography 2009-09-19 /pmc/articles/PMC2970315/ /pubmed/21577746 http://dx.doi.org/10.1107/S1600536809036848 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Xianlin Xing, Huihui Miao, Jing Jia, Maomao Chen, Zilu Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2) O (4),O (5)]bis(1,10-phenanthroline-κ(2) N,N′)dysprosium(III) dihydrate |
| title | Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2)
O
(4),O
(5)]bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) dihydrate |
| title_full | Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2)
O
(4),O
(5)]bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) dihydrate |
| title_fullStr | Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2)
O
(4),O
(5)]bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) dihydrate |
| title_full_unstemmed | Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2)
O
(4),O
(5)]bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) dihydrate |
| title_short | Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2)
O
(4),O
(5)]bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) dihydrate |
| title_sort | bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5−)-κ(2)
o
(4),o
(5)]bis(1,10-phenanthroline-κ(2)
n,n′)dysprosium(iii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970315/ https://www.ncbi.nlm.nih.gov/pubmed/21577746 http://dx.doi.org/10.1107/S1600536809036848 |
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