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catena-Poly[[trimethyl­tin(IV)]-μ-2-(2-chloro­phenyl)­acetato]

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(8)H(6)ClO(2))](n), the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxyl­ate O atoms of the 2-chloro­phenyl­acetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. A...

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Detalles Bibliográficos
Autores principales: Wen, Liyuan, Yin, Handong, Li, Wenkuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970316/
https://www.ncbi.nlm.nih.gov/pubmed/21577773
http://dx.doi.org/10.1107/S1600536809038872
Descripción
Sumario:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(8)H(6)ClO(2))](n), the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxyl­ate O atoms of the 2-chloro­phenyl­acetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 2-chloro­phenyl­acetato ligand, forming a chain structure.