Cargando…
15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid
The title compound, C(26)H(37)NO(5), which was synthesized from monoethanolamine and maleopimaric acid, consists of two fused and unbridged cyclohexane rings. They form a trans ring junction with a chair conformation. The two methyl groups are in axial positions. In the crystal, intermolecular O—...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970322/ https://www.ncbi.nlm.nih.gov/pubmed/21577898 http://dx.doi.org/10.1107/S1600536809032954 |
| _version_ | 1782190412011667456 |
|---|---|
| author | Xu, Xu Song, Zhan-qian Shang, Shi-bin Wang, Hong-xiao Rao, Xiao-ping |
| author_facet | Xu, Xu Song, Zhan-qian Shang, Shi-bin Wang, Hong-xiao Rao, Xiao-ping |
| author_sort | Xu, Xu |
| collection | PubMed |
| description | The title compound, C(26)H(37)NO(5), which was synthesized from monoethanolamine and maleopimaric acid, consists of two fused and unbridged cyclohexane rings. They form a trans ring junction with a chair conformation. The two methyl groups are in axial positions. In the crystal, intermolecular O—H⋯O hydrogen bonds link adjacent molecules into a layer structure. Two C—H⋯O interactions are also present. |
| format | Text |
| id | pubmed-2970322 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29703222010-12-30 15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid Xu, Xu Song, Zhan-qian Shang, Shi-bin Wang, Hong-xiao Rao, Xiao-ping Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(37)NO(5), which was synthesized from monoethanolamine and maleopimaric acid, consists of two fused and unbridged cyclohexane rings. They form a trans ring junction with a chair conformation. The two methyl groups are in axial positions. In the crystal, intermolecular O—H⋯O hydrogen bonds link adjacent molecules into a layer structure. Two C—H⋯O interactions are also present. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970322/ /pubmed/21577898 http://dx.doi.org/10.1107/S1600536809032954 Text en © Xu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Xu, Xu Song, Zhan-qian Shang, Shi-bin Wang, Hong-xiao Rao, Xiao-ping 15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid |
| title | 15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid |
| title_full | 15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid |
| title_fullStr | 15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid |
| title_full_unstemmed | 15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid |
| title_short | 15-Hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid |
| title_sort | 15-hydroxyethyl-19-isopropyl-5,9-dimethyl-14,16-dioxo-15-azapentacyclo[10.5.2.0(1,10).0(4,9).0(13,17)]nonadec-18-ene-5-carboxylic acid |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970322/ https://www.ncbi.nlm.nih.gov/pubmed/21577898 http://dx.doi.org/10.1107/S1600536809032954 |
| work_keys_str_mv | AT xuxu 15hydroxyethyl19isopropyl59dimethyl1416dioxo15azapentacyclo1052011004901317nonadec18ene5carboxylicacid AT songzhanqian 15hydroxyethyl19isopropyl59dimethyl1416dioxo15azapentacyclo1052011004901317nonadec18ene5carboxylicacid AT shangshibin 15hydroxyethyl19isopropyl59dimethyl1416dioxo15azapentacyclo1052011004901317nonadec18ene5carboxylicacid AT wanghongxiao 15hydroxyethyl19isopropyl59dimethyl1416dioxo15azapentacyclo1052011004901317nonadec18ene5carboxylicacid AT raoxiaoping 15hydroxyethyl19isopropyl59dimethyl1416dioxo15azapentacyclo1052011004901317nonadec18ene5carboxylicacid |