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Tetrakis(μ-4-methoxybenzoato)bis[(4-methoxybenzoato)(1,10-phenanthroline)terbium(III)]
In the title dinuclear complex, [Tb(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)], each Tb(III) ion is eight-coordinated by two N atoms from a 1,10-phenanthroline ligand and six O atoms from the carboxylate groups of five 4-methoxybenzoate ligands in a distorted square-antiprismatic geometry. All six 4-...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970326/ https://www.ncbi.nlm.nih.gov/pubmed/21577758 http://dx.doi.org/10.1107/S1600536809037751 |
Sumario: | In the title dinuclear complex, [Tb(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)], each Tb(III) ion is eight-coordinated by two N atoms from a 1,10-phenanthroline ligand and six O atoms from the carboxylate groups of five 4-methoxybenzoate ligands in a distorted square-antiprismatic geometry. All six 4-methoxybenzoate ligands act in a bidentate mode, two coordinating to one Tb center each and the other four bridging two Tb centers [Tb⋯Tb separation = 4.3144 (6) Å]. In the crystal, intermolecular π–π interactions between the aromatic rings of 1,10-phenanthroline and 4-methoxybenzoate ligands [centroid–centroid distance = 3.742 (9) Å] link two molecules into a centrosymmetric dimer. Weak intermolecular C—H⋯O hydrogen bonds help to consolidate the crystal packing. |
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