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Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)]

In the title dinuclear complex, [Tb(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)], each Tb(III) ion is eight-coordinated by two N atoms from a 1,10-phenanthroline ligand and six O atoms from the carboxyl­ate groups of five 4-methoxy­benzoate ligands in a distorted square-anti­prismatic geometry. All six 4-...

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Detalles Bibliográficos
Autores principales: Gao, Zhi-Hua, Wang, Hao, He, Jing-Yu, Wang, Rui-Fen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970326/
https://www.ncbi.nlm.nih.gov/pubmed/21577758
http://dx.doi.org/10.1107/S1600536809037751
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author Gao, Zhi-Hua
Wang, Hao
He, Jing-Yu
Wang, Rui-Fen
author_facet Gao, Zhi-Hua
Wang, Hao
He, Jing-Yu
Wang, Rui-Fen
author_sort Gao, Zhi-Hua
collection PubMed
description In the title dinuclear complex, [Tb(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)], each Tb(III) ion is eight-coordinated by two N atoms from a 1,10-phenanthroline ligand and six O atoms from the carboxyl­ate groups of five 4-methoxy­benzoate ligands in a distorted square-anti­prismatic geometry. All six 4-methoxy­benzoate ligands act in a bidentate mode, two coordinating to one Tb center each and the other four bridging two Tb centers [Tb⋯Tb separation = 4.3144 (6) Å]. In the crystal, inter­molecular π–π inter­actions between the aromatic rings of 1,10-phenanthroline and 4-methoxy­benzoate ligands [centroid–centroid distance = 3.742 (9) Å] link two mol­ecules into a centrosymmetric dimer. Weak inter­molecular C—H⋯O hydrogen bonds help to consolidate the crystal packing.
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spelling pubmed-29703262010-12-30 Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)] Gao, Zhi-Hua Wang, Hao He, Jing-Yu Wang, Rui-Fen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Tb(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)], each Tb(III) ion is eight-coordinated by two N atoms from a 1,10-phenanthroline ligand and six O atoms from the carboxyl­ate groups of five 4-methoxy­benzoate ligands in a distorted square-anti­prismatic geometry. All six 4-methoxy­benzoate ligands act in a bidentate mode, two coordinating to one Tb center each and the other four bridging two Tb centers [Tb⋯Tb separation = 4.3144 (6) Å]. In the crystal, inter­molecular π–π inter­actions between the aromatic rings of 1,10-phenanthroline and 4-methoxy­benzoate ligands [centroid–centroid distance = 3.742 (9) Å] link two mol­ecules into a centrosymmetric dimer. Weak inter­molecular C—H⋯O hydrogen bonds help to consolidate the crystal packing. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970326/ /pubmed/21577758 http://dx.doi.org/10.1107/S1600536809037751 Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhi-Hua
Wang, Hao
He, Jing-Yu
Wang, Rui-Fen
Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)]
title Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)]
title_full Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)]
title_fullStr Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)]
title_full_unstemmed Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)]
title_short Tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(III)]
title_sort tetra­kis(μ-4-methoxy­benzoato)bis­[(4-methoxy­benzoato)(1,10-phenan­throline)terbium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970326/
https://www.ncbi.nlm.nih.gov/pubmed/21577758
http://dx.doi.org/10.1107/S1600536809037751
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