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Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetradentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The –CH(2)–CH(2)– group of the ligand is disordered equally over...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970327/ https://www.ncbi.nlm.nih.gov/pubmed/21577698 http://dx.doi.org/10.1107/S1600536809034278 |
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author | Guo, Zhenghua Li, Lianzhi Xu, Tao Li, Jinghong Wang, Daqi |
author_facet | Guo, Zhenghua Li, Lianzhi Xu, Tao Li, Jinghong Wang, Daqi |
author_sort | Guo, Zhenghua |
collection | PubMed |
description | The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetradentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The –CH(2)–CH(2)– group of the ligand is disordered equally over two sites about the mirror plane. The dihedral angle between the mean planes of the two symmetry-related chelate rings is 37.16 (6)°. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link complex molecules into one-dimensional chains along [100] and these chains are linked, in turn, by very weak intermolecular C—H⋯O hydrogen bonds into a two-dimensional network. |
format | Text |
id | pubmed-2970327 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29703272010-12-30 Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) Guo, Zhenghua Li, Lianzhi Xu, Tao Li, Jinghong Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetradentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The –CH(2)–CH(2)– group of the ligand is disordered equally over two sites about the mirror plane. The dihedral angle between the mean planes of the two symmetry-related chelate rings is 37.16 (6)°. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link complex molecules into one-dimensional chains along [100] and these chains are linked, in turn, by very weak intermolecular C—H⋯O hydrogen bonds into a two-dimensional network. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970327/ /pubmed/21577698 http://dx.doi.org/10.1107/S1600536809034278 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Zhenghua Li, Lianzhi Xu, Tao Li, Jinghong Wang, Daqi Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) |
title | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) |
title_full | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) |
title_fullStr | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) |
title_full_unstemmed | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) |
title_short | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) |
title_sort | aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970327/ https://www.ncbi.nlm.nih.gov/pubmed/21577698 http://dx.doi.org/10.1107/S1600536809034278 |
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