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Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)

The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetra­dentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The –CH(2)–CH(2)– group of the ligand is disordered equally over...

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Detalles Bibliográficos
Autores principales: Guo, Zhenghua, Li, Lianzhi, Xu, Tao, Li, Jinghong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970327/
https://www.ncbi.nlm.nih.gov/pubmed/21577698
http://dx.doi.org/10.1107/S1600536809034278
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author Guo, Zhenghua
Li, Lianzhi
Xu, Tao
Li, Jinghong
Wang, Daqi
author_facet Guo, Zhenghua
Li, Lianzhi
Xu, Tao
Li, Jinghong
Wang, Daqi
author_sort Guo, Zhenghua
collection PubMed
description The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetra­dentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The –CH(2)–CH(2)– group of the ligand is disordered equally over two sites about the mirror plane. The dihedral angle between the mean planes of the two symmetry-related chelate rings is 37.16 (6)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into one-dimensional chains along [100] and these chains are linked, in turn, by very weak inter­molecular C—H⋯O hydrogen bonds into a two-dimensional network.
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spelling pubmed-29703272010-12-30 Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II) Guo, Zhenghua Li, Lianzhi Xu, Tao Li, Jinghong Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetra­dentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The –CH(2)–CH(2)– group of the ligand is disordered equally over two sites about the mirror plane. The dihedral angle between the mean planes of the two symmetry-related chelate rings is 37.16 (6)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into one-dimensional chains along [100] and these chains are linked, in turn, by very weak inter­molecular C—H⋯O hydrogen bonds into a two-dimensional network. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970327/ /pubmed/21577698 http://dx.doi.org/10.1107/S1600536809034278 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Zhenghua
Li, Lianzhi
Xu, Tao
Li, Jinghong
Wang, Daqi
Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_fullStr Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full_unstemmed Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_short Aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_sort aqua­{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970327/
https://www.ncbi.nlm.nih.gov/pubmed/21577698
http://dx.doi.org/10.1107/S1600536809034278
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