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N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate
In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base molecule is approximately planar [within 0.189 (1) Å]. The interplanar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, molecules are linked into a three-dimensional network by strong and weak O—H⋯O...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970332/ https://www.ncbi.nlm.nih.gov/pubmed/21577961 http://dx.doi.org/10.1107/S1600536809037489 |
Sumario: | In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base molecule is approximately planar [within 0.189 (1) Å]. The interplanar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, molecules are linked into a three-dimensional network by strong and weak O—H⋯O and strong N—H⋯O hydrogen bonds. The hydroxy H atom deviates from the 4-hydroxy-3-methoxyphenyl mean plane by 0.319 (2) Å, probably due to the involvement of this H atom in the O—H⋯O hydrogen bond. The weak O—H⋯O hydrogen bond is involved in a bifurcated hydrogen bond with R (1) (2)(4) motif. A weak C—H⋯π interaction is also present. |
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