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N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate

In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base mol­ecule is approximately planar [within 0.189 (1) Å]. The inter­planar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, mol­ecules are linked into a three-dimensional network by strong and weak O—H⋯O...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Wen-Bo, Tan, Ying, Zhang, Yong-Zhao, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970332/
https://www.ncbi.nlm.nih.gov/pubmed/21577961
http://dx.doi.org/10.1107/S1600536809037489
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author Lv, Lu-Ping
Yu, Wen-Bo
Tan, Ying
Zhang, Yong-Zhao
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Wen-Bo
Tan, Ying
Zhang, Yong-Zhao
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base mol­ecule is approximately planar [within 0.189 (1) Å]. The inter­planar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, mol­ecules are linked into a three-dimensional network by strong and weak O—H⋯O and strong N—H⋯O hydrogen bonds. The hydr­oxy H atom deviates from the 4-hydr­oxy-3-methoxy­phenyl mean plane by 0.319 (2) Å, probably due to the involvement of this H atom in the O—H⋯O hydrogen bond. The weak O—H⋯O hydrogen bond is involved in a bifurcated hydrogen bond with R (1) (2)(4) motif. A weak C—H⋯π inter­action is also present.
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spelling pubmed-29703322010-12-30 N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate Lv, Lu-Ping Yu, Wen-Bo Tan, Ying Zhang, Yong-Zhao Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base mol­ecule is approximately planar [within 0.189 (1) Å]. The inter­planar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, mol­ecules are linked into a three-dimensional network by strong and weak O—H⋯O and strong N—H⋯O hydrogen bonds. The hydr­oxy H atom deviates from the 4-hydr­oxy-3-methoxy­phenyl mean plane by 0.319 (2) Å, probably due to the involvement of this H atom in the O—H⋯O hydrogen bond. The weak O—H⋯O hydrogen bond is involved in a bifurcated hydrogen bond with R (1) (2)(4) motif. A weak C—H⋯π inter­action is also present. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970332/ /pubmed/21577961 http://dx.doi.org/10.1107/S1600536809037489 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Wen-Bo
Tan, Ying
Zhang, Yong-Zhao
Hu, Xian-Chao
N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate
title N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate
title_full N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate
title_fullStr N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate
title_full_unstemmed N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate
title_short N′-(4-Hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate
title_sort n′-(4-hydr­oxy-3-methoxy­benzyl­idene)acetohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970332/
https://www.ncbi.nlm.nih.gov/pubmed/21577961
http://dx.doi.org/10.1107/S1600536809037489
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