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N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate
In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base molecule is approximately planar [within 0.189 (1) Å]. The interplanar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, molecules are linked into a three-dimensional network by strong and weak O—H⋯O...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970332/ https://www.ncbi.nlm.nih.gov/pubmed/21577961 http://dx.doi.org/10.1107/S1600536809037489 |
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author | Lv, Lu-Ping Yu, Wen-Bo Tan, Ying Zhang, Yong-Zhao Hu, Xian-Chao |
author_facet | Lv, Lu-Ping Yu, Wen-Bo Tan, Ying Zhang, Yong-Zhao Hu, Xian-Chao |
author_sort | Lv, Lu-Ping |
collection | PubMed |
description | In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base molecule is approximately planar [within 0.189 (1) Å]. The interplanar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, molecules are linked into a three-dimensional network by strong and weak O—H⋯O and strong N—H⋯O hydrogen bonds. The hydroxy H atom deviates from the 4-hydroxy-3-methoxyphenyl mean plane by 0.319 (2) Å, probably due to the involvement of this H atom in the O—H⋯O hydrogen bond. The weak O—H⋯O hydrogen bond is involved in a bifurcated hydrogen bond with R (1) (2)(4) motif. A weak C—H⋯π interaction is also present. |
format | Text |
id | pubmed-2970332 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29703322010-12-30 N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate Lv, Lu-Ping Yu, Wen-Bo Tan, Ying Zhang, Yong-Zhao Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(12)N(2)O(3)·H(2)O, the Schiff base molecule is approximately planar [within 0.189 (1) Å]. The interplanar angle between the benzene and acetohydrazide planes is 8.50 (10)°. In the crystal, molecules are linked into a three-dimensional network by strong and weak O—H⋯O and strong N—H⋯O hydrogen bonds. The hydroxy H atom deviates from the 4-hydroxy-3-methoxyphenyl mean plane by 0.319 (2) Å, probably due to the involvement of this H atom in the O—H⋯O hydrogen bond. The weak O—H⋯O hydrogen bond is involved in a bifurcated hydrogen bond with R (1) (2)(4) motif. A weak C—H⋯π interaction is also present. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970332/ /pubmed/21577961 http://dx.doi.org/10.1107/S1600536809037489 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Lv, Lu-Ping Yu, Wen-Bo Tan, Ying Zhang, Yong-Zhao Hu, Xian-Chao N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate |
title |
N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate |
title_full |
N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate |
title_fullStr |
N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate |
title_full_unstemmed |
N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate |
title_short |
N′-(4-Hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate |
title_sort | n′-(4-hydroxy-3-methoxybenzylidene)acetohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970332/ https://www.ncbi.nlm.nih.gov/pubmed/21577961 http://dx.doi.org/10.1107/S1600536809037489 |
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