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Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3) O (1):O (4),O (4′);κ(3) O (1),O (1′):O (4)-bis[aqua(1,10-phenanthroline-κ(2) N,N′)zinc(II)]
The cyclohexane-1,3-dicarboxylate dianion in the dinuclear centrosymmetric title compound, [Zn(2)(C(8)H(10)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], has a chair conformation with both carboxylate groups in equatorial positions. One carboxylate group chelates a Zn(II) atom, whereas the other binds t...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970336/ https://www.ncbi.nlm.nih.gov/pubmed/21577713 http://dx.doi.org/10.1107/S1600536809035144 |
| _version_ | 1782190415842115584 |
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| author | Rizal, Mohd. Razali Ng, Seik Weng |
| author_facet | Rizal, Mohd. Razali Ng, Seik Weng |
| author_sort | Rizal, Mohd. Razali |
| collection | PubMed |
| description | The cyclohexane-1,3-dicarboxylate dianion in the dinuclear centrosymmetric title compound, [Zn(2)(C(8)H(10)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], has a chair conformation with both carboxylate groups in equatorial positions. One carboxylate group chelates a Zn(II) atom, whereas the other binds through one O atom only to confer a six-coordinate status to the N-heterocycle-chelated water-coordinated Zn(II) atom. Adjacent dinuclear molecules are linked by O—H⋯O hydrogen bonds into a linear chain. |
| format | Text |
| id | pubmed-2970336 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29703362010-12-30 Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3) O (1):O (4),O (4′);κ(3) O (1),O (1′):O (4)-bis[aqua(1,10-phenanthroline-κ(2) N,N′)zinc(II)] Rizal, Mohd. Razali Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The cyclohexane-1,3-dicarboxylate dianion in the dinuclear centrosymmetric title compound, [Zn(2)(C(8)H(10)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], has a chair conformation with both carboxylate groups in equatorial positions. One carboxylate group chelates a Zn(II) atom, whereas the other binds through one O atom only to confer a six-coordinate status to the N-heterocycle-chelated water-coordinated Zn(II) atom. Adjacent dinuclear molecules are linked by O—H⋯O hydrogen bonds into a linear chain. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970336/ /pubmed/21577713 http://dx.doi.org/10.1107/S1600536809035144 Text en © Rizal and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Rizal, Mohd. Razali Ng, Seik Weng Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3) O (1):O (4),O (4′);κ(3) O (1),O (1′):O (4)-bis[aqua(1,10-phenanthroline-κ(2) N,N′)zinc(II)] |
| title | Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3)
O
(1):O
(4),O
(4′);κ(3)
O
(1),O
(1′):O
(4)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)zinc(II)] |
| title_full | Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3)
O
(1):O
(4),O
(4′);κ(3)
O
(1),O
(1′):O
(4)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)zinc(II)] |
| title_fullStr | Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3)
O
(1):O
(4),O
(4′);κ(3)
O
(1),O
(1′):O
(4)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)zinc(II)] |
| title_full_unstemmed | Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3)
O
(1):O
(4),O
(4′);κ(3)
O
(1),O
(1′):O
(4)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)zinc(II)] |
| title_short | Bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3)
O
(1):O
(4),O
(4′);κ(3)
O
(1),O
(1′):O
(4)-bis[aqua(1,10-phenanthroline-κ(2)
N,N′)zinc(II)] |
| title_sort | bis(μ-cyclohexane-1,3-dicarboxylato)-κ(3)
o
(1):o
(4),o
(4′);κ(3)
o
(1),o
(1′):o
(4)-bis[aqua(1,10-phenanthroline-κ(2)
n,n′)zinc(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970336/ https://www.ncbi.nlm.nih.gov/pubmed/21577713 http://dx.doi.org/10.1107/S1600536809035144 |
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