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1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate

The title compound, [Fe(C(5)H(5))(C(30)H(32)O(7)P)], which is an inter­mediate in the synthesis of (R (p))-2-(diphenyl­phos­phino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P2(1)2(1)2(1). In general, the mol­ecular geometry is very similar to that of the corresponding...

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Detalles Bibliográficos
Autores principales: Štěpnička, Petr, Lamač, Martin, Císařová, Ivana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970338/
https://www.ncbi.nlm.nih.gov/pubmed/21577768
http://dx.doi.org/10.1107/S1600536809038653
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author Štěpnička, Petr
Lamač, Martin
Císařová, Ivana
author_facet Štěpnička, Petr
Lamač, Martin
Císařová, Ivana
author_sort Štěpnička, Petr
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(30)H(32)O(7)P)], which is an inter­mediate in the synthesis of (R (p))-2-(diphenyl­phos­phino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P2(1)2(1)2(1). In general, the mol­ecular geometry is very similar to that of the corresponding 2,1′-bis­(diphenyl­phosphino) congener. The ferrocene unit assumes a regular geometry with the proximal bulky substituents efficiently avoiding mutual spatial contacts. In the crystal, the mol­ecules participate in weak intra- and inter­molecular C—H⋯O inter­actions.
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spelling pubmed-29703382010-12-30 1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate Štěpnička, Petr Lamač, Martin Císařová, Ivana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(30)H(32)O(7)P)], which is an inter­mediate in the synthesis of (R (p))-2-(diphenyl­phos­phino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P2(1)2(1)2(1). In general, the mol­ecular geometry is very similar to that of the corresponding 2,1′-bis­(diphenyl­phosphino) congener. The ferrocene unit assumes a regular geometry with the proximal bulky substituents efficiently avoiding mutual spatial contacts. In the crystal, the mol­ecules participate in weak intra- and inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970338/ /pubmed/21577768 http://dx.doi.org/10.1107/S1600536809038653 Text en © Štěpnička et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Štěpnička, Petr
Lamač, Martin
Císařová, Ivana
1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate
title 1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate
title_full 1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate
title_fullStr 1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate
title_full_unstemmed 1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate
title_short 1,2:5,6-Di-O-isopropyl­idene-α-d-3-glucofuranosyl (R (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate
title_sort 1,2:5,6-di-o-isopropyl­idene-α-d-3-glucofuranosyl (r (p))-2-(diphenyl­phosphino)ferrocene-1-carboxyl­ate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970338/
https://www.ncbi.nlm.nih.gov/pubmed/21577768
http://dx.doi.org/10.1107/S1600536809038653
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