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1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R (p))-2-(diphenylphosphino)ferrocene-1-carboxylate
The title compound, [Fe(C(5)H(5))(C(30)H(32)O(7)P)], which is an intermediate in the synthesis of (R (p))-2-(diphenylphosphino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P2(1)2(1)2(1). In general, the molecular geometry is very similar to that of the corresponding...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970338/ https://www.ncbi.nlm.nih.gov/pubmed/21577768 http://dx.doi.org/10.1107/S1600536809038653 |
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author | Štěpnička, Petr Lamač, Martin Císařová, Ivana |
author_facet | Štěpnička, Petr Lamač, Martin Císařová, Ivana |
author_sort | Štěpnička, Petr |
collection | PubMed |
description | The title compound, [Fe(C(5)H(5))(C(30)H(32)O(7)P)], which is an intermediate in the synthesis of (R (p))-2-(diphenylphosphino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P2(1)2(1)2(1). In general, the molecular geometry is very similar to that of the corresponding 2,1′-bis(diphenylphosphino) congener. The ferrocene unit assumes a regular geometry with the proximal bulky substituents efficiently avoiding mutual spatial contacts. In the crystal, the molecules participate in weak intra- and intermolecular C—H⋯O interactions. |
format | Text |
id | pubmed-2970338 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29703382010-12-30 1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R (p))-2-(diphenylphosphino)ferrocene-1-carboxylate Štěpnička, Petr Lamač, Martin Císařová, Ivana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(30)H(32)O(7)P)], which is an intermediate in the synthesis of (R (p))-2-(diphenylphosphino)ferrocene-1-carboxylic acid, crystallizes in the common chiral space group P2(1)2(1)2(1). In general, the molecular geometry is very similar to that of the corresponding 2,1′-bis(diphenylphosphino) congener. The ferrocene unit assumes a regular geometry with the proximal bulky substituents efficiently avoiding mutual spatial contacts. In the crystal, the molecules participate in weak intra- and intermolecular C—H⋯O interactions. International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970338/ /pubmed/21577768 http://dx.doi.org/10.1107/S1600536809038653 Text en © Štěpnička et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Štěpnička, Petr Lamač, Martin Císařová, Ivana 1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R (p))-2-(diphenylphosphino)ferrocene-1-carboxylate |
title | 1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R
(p))-2-(diphenylphosphino)ferrocene-1-carboxylate |
title_full | 1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R
(p))-2-(diphenylphosphino)ferrocene-1-carboxylate |
title_fullStr | 1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R
(p))-2-(diphenylphosphino)ferrocene-1-carboxylate |
title_full_unstemmed | 1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R
(p))-2-(diphenylphosphino)ferrocene-1-carboxylate |
title_short | 1,2:5,6-Di-O-isopropylidene-α-d-3-glucofuranosyl (R
(p))-2-(diphenylphosphino)ferrocene-1-carboxylate |
title_sort | 1,2:5,6-di-o-isopropylidene-α-d-3-glucofuranosyl (r
(p))-2-(diphenylphosphino)ferrocene-1-carboxylate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970338/ https://www.ncbi.nlm.nih.gov/pubmed/21577768 http://dx.doi.org/10.1107/S1600536809038653 |
work_keys_str_mv | AT stepnickapetr 1256dioisopropylidenead3glucofuranosylrp2diphenylphosphinoferrocene1carboxylate AT lamacmartin 1256dioisopropylidenead3glucofuranosylrp2diphenylphosphinoferrocene1carboxylate AT cisarovaivana 1256dioisopropylidenead3glucofuranosylrp2diphenylphosphinoferrocene1carboxylate |