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catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2) N (2):O]
In the polymeric title complex, [Cu(C(7)H(3)N(2)O(2)S)(2)(H(2)O)(2)](n), the Cu(II) centre is surrounded by three 1,2,3-benzothiadiazole-7-carboxylate and two water molecules. A 1,2,3-benzothiadiazole-7-carboxylate ligand bridges two Cu(II) centres, with a Cu⋯Cu distance of 9.006 (2) Å. The fou...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970341/ https://www.ncbi.nlm.nih.gov/pubmed/21577716 http://dx.doi.org/10.1107/S1600536809032036 |
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author | Zhang, Guo-Ying Zhang, Xin Xu, Hai-Zhen |
author_facet | Zhang, Guo-Ying Zhang, Xin Xu, Hai-Zhen |
author_sort | Zhang, Guo-Ying |
collection | PubMed |
description | In the polymeric title complex, [Cu(C(7)H(3)N(2)O(2)S)(2)(H(2)O)(2)](n), the Cu(II) centre is surrounded by three 1,2,3-benzothiadiazole-7-carboxylate and two water molecules. A 1,2,3-benzothiadiazole-7-carboxylate ligand bridges two Cu(II) centres, with a Cu⋯Cu distance of 9.006 (2) Å. The four O atoms in the equatorial planes around each Cu(II) centre form a distorted square-planar arrangement, while the distorted square-pyramidal coordination is completed by the symmetry-related N atoms of the bridging 1,2,3-benzothiadiazole-7-carboxylate ligands. In the crystal structure, intermolecular O—H⋯O and O—H⋯N hydrogen bonds link the molecules into a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2970341 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29703412010-12-30 catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2) N (2):O] Zhang, Guo-Ying Zhang, Xin Xu, Hai-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, [Cu(C(7)H(3)N(2)O(2)S)(2)(H(2)O)(2)](n), the Cu(II) centre is surrounded by three 1,2,3-benzothiadiazole-7-carboxylate and two water molecules. A 1,2,3-benzothiadiazole-7-carboxylate ligand bridges two Cu(II) centres, with a Cu⋯Cu distance of 9.006 (2) Å. The four O atoms in the equatorial planes around each Cu(II) centre form a distorted square-planar arrangement, while the distorted square-pyramidal coordination is completed by the symmetry-related N atoms of the bridging 1,2,3-benzothiadiazole-7-carboxylate ligands. In the crystal structure, intermolecular O—H⋯O and O—H⋯N hydrogen bonds link the molecules into a three-dimensional supramolecular network. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970341/ /pubmed/21577716 http://dx.doi.org/10.1107/S1600536809032036 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Guo-Ying Zhang, Xin Xu, Hai-Zhen catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2) N (2):O] |
title |
catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2)
N
(2):O] |
title_full |
catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2)
N
(2):O] |
title_fullStr |
catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2)
N
(2):O] |
title_full_unstemmed |
catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2)
N
(2):O] |
title_short |
catena-Poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κO)copper(II)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2)
N
(2):O] |
title_sort | catena-poly[[diaqua(1,2,3-benzothiadiazole-7-carboxylato-κo)copper(ii)]-μ-1,2,3-benzothiadiazole-7-carboxylato-κ(2)
n
(2):o] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970341/ https://www.ncbi.nlm.nih.gov/pubmed/21577716 http://dx.doi.org/10.1107/S1600536809032036 |
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