Cargando…

catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O]

In the polymeric title complex, [Cu(C(7)H(3)N(2)O(2)S)(2)(H(2)O)(2)](n), the Cu(II) centre is surrounded by three 1,2,3-benzothia­diazole-7-carboxyl­ate and two water mol­ecules. A 1,2,3-benzothia­diazole-7-carboxyl­ate ligand bridges two Cu(II) centres, with a Cu⋯Cu distance of 9.006 (2) Å. The fou...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Guo-Ying, Zhang, Xin, Xu, Hai-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970341/
https://www.ncbi.nlm.nih.gov/pubmed/21577716
http://dx.doi.org/10.1107/S1600536809032036
_version_ 1782190417013374976
author Zhang, Guo-Ying
Zhang, Xin
Xu, Hai-Zhen
author_facet Zhang, Guo-Ying
Zhang, Xin
Xu, Hai-Zhen
author_sort Zhang, Guo-Ying
collection PubMed
description In the polymeric title complex, [Cu(C(7)H(3)N(2)O(2)S)(2)(H(2)O)(2)](n), the Cu(II) centre is surrounded by three 1,2,3-benzothia­diazole-7-carboxyl­ate and two water mol­ecules. A 1,2,3-benzothia­diazole-7-carboxyl­ate ligand bridges two Cu(II) centres, with a Cu⋯Cu distance of 9.006 (2) Å. The four O atoms in the equatorial planes around each Cu(II) centre form a distorted square-planar arrangement, while the distorted square-pyramidal coordination is completed by the symmetry-related N atoms of the bridging 1,2,3-benzothia­diazole-7-carboxyl­ate ligands. In the crystal structure, inter­molecular O—H⋯O and O—H⋯N hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network.
format Text
id pubmed-2970341
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29703412010-12-30 catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O] Zhang, Guo-Ying Zhang, Xin Xu, Hai-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, [Cu(C(7)H(3)N(2)O(2)S)(2)(H(2)O)(2)](n), the Cu(II) centre is surrounded by three 1,2,3-benzothia­diazole-7-carboxyl­ate and two water mol­ecules. A 1,2,3-benzothia­diazole-7-carboxyl­ate ligand bridges two Cu(II) centres, with a Cu⋯Cu distance of 9.006 (2) Å. The four O atoms in the equatorial planes around each Cu(II) centre form a distorted square-planar arrangement, while the distorted square-pyramidal coordination is completed by the symmetry-related N atoms of the bridging 1,2,3-benzothia­diazole-7-carboxyl­ate ligands. In the crystal structure, inter­molecular O—H⋯O and O—H⋯N hydrogen bonds link the mol­ecules into a three-dimensional supra­molecular network. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970341/ /pubmed/21577716 http://dx.doi.org/10.1107/S1600536809032036 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Guo-Ying
Zhang, Xin
Xu, Hai-Zhen
catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O]
title catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O]
title_full catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O]
title_fullStr catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O]
title_full_unstemmed catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O]
title_short catena-Poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κO)copper(II)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) N (2):O]
title_sort catena-poly[[diaqua­(1,2,3-benzothia­diazole-7-carboxyl­ato-κo)copper(ii)]-μ-1,2,3-benzothia­diazole-7-carboxyl­ato-κ(2) n (2):o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970341/
https://www.ncbi.nlm.nih.gov/pubmed/21577716
http://dx.doi.org/10.1107/S1600536809032036
work_keys_str_mv AT zhangguoying catenapolydiaqua123benzothiadiazole7carboxylatokocopperiim123benzothiadiazole7carboxylatok2n2o
AT zhangxin catenapolydiaqua123benzothiadiazole7carboxylatokocopperiim123benzothiadiazole7carboxylatok2n2o
AT xuhaizhen catenapolydiaqua123benzothiadiazole7carboxylatokocopperiim123benzothiadiazole7carboxylatok2n2o