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4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one
In the title molecule, C(35)H(22)BrNO(2), the four-membered ring of the β-lactam unit is nearly planar [maximum deviation = 0.003 (3) Å] and makes dihedral angles of 87.07 (15), 59.80 (16) and 20.81 (19)°, respectively, with the xanthene system, the anthracene system and the bromo-substituted benze...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970342/ https://www.ncbi.nlm.nih.gov/pubmed/21577969 http://dx.doi.org/10.1107/S1600536809037830 |
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| author | Çelik, Ísmail Akkurt, Mehmet Jarrahpour, Aliasghar Ebrahimi, Edris Büyükgüngör, Orhan |
| author_facet | Çelik, Ísmail Akkurt, Mehmet Jarrahpour, Aliasghar Ebrahimi, Edris Büyükgüngör, Orhan |
| author_sort | Çelik, Ísmail |
| collection | PubMed |
| description | In the title molecule, C(35)H(22)BrNO(2), the four-membered ring of the β-lactam unit is nearly planar [maximum deviation = 0.003 (3) Å] and makes dihedral angles of 87.07 (15), 59.80 (16) and 20.81 (19)°, respectively, with the xanthene system, the anthracene system and the bromo-substituted benzene ring. The molecular conformation is stabilized by weak intramolecular C—H⋯O and C—H⋯N hydrogen bonds. The crystal structure features weak C—H⋯π interactions. |
| format | Text |
| id | pubmed-2970342 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29703422010-12-30 4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one Çelik, Ísmail Akkurt, Mehmet Jarrahpour, Aliasghar Ebrahimi, Edris Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(35)H(22)BrNO(2), the four-membered ring of the β-lactam unit is nearly planar [maximum deviation = 0.003 (3) Å] and makes dihedral angles of 87.07 (15), 59.80 (16) and 20.81 (19)°, respectively, with the xanthene system, the anthracene system and the bromo-substituted benzene ring. The molecular conformation is stabilized by weak intramolecular C—H⋯O and C—H⋯N hydrogen bonds. The crystal structure features weak C—H⋯π interactions. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970342/ /pubmed/21577969 http://dx.doi.org/10.1107/S1600536809037830 Text en © Çelik et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Çelik, Ísmail Akkurt, Mehmet Jarrahpour, Aliasghar Ebrahimi, Edris Büyükgüngör, Orhan 4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one |
| title | 4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one |
| title_full | 4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one |
| title_fullStr | 4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one |
| title_full_unstemmed | 4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one |
| title_short | 4-(9-Anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one |
| title_sort | 4-(9-anthryl)-1-(3-bromophenyl)spiro[azetidine-3,9′-xanthen]-2-one |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970342/ https://www.ncbi.nlm.nih.gov/pubmed/21577969 http://dx.doi.org/10.1107/S1600536809037830 |
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