Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)

In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O—H⋯O and O—H⋯Cl hydrogen bonds involving hydr­oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a π–π stacking inter­action b...

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Detalles Bibliográficos
Autores principales: Zhang, Shi Guo, Xie, Long Miao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970345/
https://www.ncbi.nlm.nih.gov/pubmed/21577753
http://dx.doi.org/10.1107/S1600536809037465
Descripción
Sumario:In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O—H⋯O and O—H⋯Cl hydrogen bonds involving hydr­oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a π–π stacking inter­action between adjacent 1,10-phenanthroline rings, with a distance of 3.675 (2) Å between the centroids of the pyridine and benzene rings.

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