Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)

In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O—H⋯O and O—H⋯Cl hydrogen bonds involving hydr­oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a π–π stacking inter­action b...

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Detalles Bibliográficos
Autores principales: Zhang, Shi Guo, Xie, Long Miao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970345/
https://www.ncbi.nlm.nih.gov/pubmed/21577753
http://dx.doi.org/10.1107/S1600536809037465
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author Zhang, Shi Guo
Xie, Long Miao
author_facet Zhang, Shi Guo
Xie, Long Miao
author_sort Zhang, Shi Guo
collection PubMed
description In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O—H⋯O and O—H⋯Cl hydrogen bonds involving hydr­oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a π–π stacking inter­action between adjacent 1,10-phenanthroline rings, with a distance of 3.675 (2) Å between the centroids of the pyridine and benzene rings.
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spelling pubmed-29703452010-12-30 Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II) Zhang, Shi Guo Xie, Long Miao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O—H⋯O and O—H⋯Cl hydrogen bonds involving hydr­oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a π–π stacking inter­action between adjacent 1,10-phenanthroline rings, with a distance of 3.675 (2) Å between the centroids of the pyridine and benzene rings. International Union of Crystallography 2009-09-19 /pmc/articles/PMC2970345/ /pubmed/21577753 http://dx.doi.org/10.1107/S1600536809037465 Text en © Zhang and Xie 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Shi Guo
Xie, Long Miao
Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)
title Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)
title_full Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)
title_fullStr Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)
title_full_unstemmed Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)
title_short Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)
title_sort dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970345/
https://www.ncbi.nlm.nih.gov/pubmed/21577753
http://dx.doi.org/10.1107/S1600536809037465
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