Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II)

The Os(II) atom in the title compound, [OsCl(2)(C(8)H(12))(C(18)H(15)P)(2)], is located on a crystallographic twofold axis and adopts a distorted octa­hedral coordination geometry. The two triphenyl­phosphine ligands are trans to each other, while the two chlorine ligands are cis-disposed. The coord...

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Detalles Bibliográficos
Autores principales: Ye, Chen, Wen, Ting Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970349/
https://www.ncbi.nlm.nih.gov/pubmed/21577759
http://dx.doi.org/10.1107/S1600536809037817
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author Ye, Chen
Wen, Ting Bin
author_facet Ye, Chen
Wen, Ting Bin
author_sort Ye, Chen
collection PubMed
description The Os(II) atom in the title compound, [OsCl(2)(C(8)H(12))(C(18)H(15)P)(2)], is located on a crystallographic twofold axis and adopts a distorted octa­hedral coordination geometry. The two triphenyl­phosphine ligands are trans to each other, while the two chlorine ligands are cis-disposed. The coordination is completed by the cyclo­octa­diene (COD) ligand with bonding to the two olefin double bonds. The C=C bond has a length of 1.403 (6) Å, which is significntly longer than a free olefinic double bond (≃1.34 Å).
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spelling pubmed-29703492010-12-30 Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II) Ye, Chen Wen, Ting Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Os(II) atom in the title compound, [OsCl(2)(C(8)H(12))(C(18)H(15)P)(2)], is located on a crystallographic twofold axis and adopts a distorted octa­hedral coordination geometry. The two triphenyl­phosphine ligands are trans to each other, while the two chlorine ligands are cis-disposed. The coordination is completed by the cyclo­octa­diene (COD) ligand with bonding to the two olefin double bonds. The C=C bond has a length of 1.403 (6) Å, which is significntly longer than a free olefinic double bond (≃1.34 Å). International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970349/ /pubmed/21577759 http://dx.doi.org/10.1107/S1600536809037817 Text en © Ye and Wen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ye, Chen
Wen, Ting Bin
Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II)
title Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II)
title_full Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II)
title_fullStr Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II)
title_full_unstemmed Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II)
title_short Dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(II)
title_sort dichlorido(η(4)-cyclo­octa-1,5-diene)bis­(triphenyl­phosphine)osmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970349/
https://www.ncbi.nlm.nih.gov/pubmed/21577759
http://dx.doi.org/10.1107/S1600536809037817
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