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Bis(acetylacetonato-κ(2) O,O′)aqua(diacetylmethanido-κC)iridium(III)
In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octahedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dio...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970352/ https://www.ncbi.nlm.nih.gov/pubmed/21577775 http://dx.doi.org/10.1107/S160053680903760X |
| _version_ | 1782190419864453120 |
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| author | Chang, Qiao-Wen Xie, Ming-Jin Liu, Wei-Ping Chen, Xi-Zhu Ye, Qing-Song |
| author_facet | Chang, Qiao-Wen Xie, Ming-Jin Liu, Wei-Ping Chen, Xi-Zhu Ye, Qing-Song |
| author_sort | Chang, Qiao-Wen |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octahedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dione and NaHCO(3). O—H⋯O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010). |
| format | Text |
| id | pubmed-2970352 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29703522010-12-30 Bis(acetylacetonato-κ(2) O,O′)aqua(diacetylmethanido-κC)iridium(III) Chang, Qiao-Wen Xie, Ming-Jin Liu, Wei-Ping Chen, Xi-Zhu Ye, Qing-Song Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ir(C(5)H(7)O(2))(3)(H(2)O)], the Ir(III) atom is six-coordinated and situated in a slightly distorted octahedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl(3)(H(2)O)(x), pentane-2,5-dione and NaHCO(3). O—H⋯O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010). International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970352/ /pubmed/21577775 http://dx.doi.org/10.1107/S160053680903760X Text en © Chang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chang, Qiao-Wen Xie, Ming-Jin Liu, Wei-Ping Chen, Xi-Zhu Ye, Qing-Song Bis(acetylacetonato-κ(2) O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title | Bis(acetylacetonato-κ(2)
O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_full | Bis(acetylacetonato-κ(2)
O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_fullStr | Bis(acetylacetonato-κ(2)
O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_full_unstemmed | Bis(acetylacetonato-κ(2)
O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_short | Bis(acetylacetonato-κ(2)
O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_sort | bis(acetylacetonato-κ(2)
o,o′)aqua(diacetylmethanido-κc)iridium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970352/ https://www.ncbi.nlm.nih.gov/pubmed/21577775 http://dx.doi.org/10.1107/S160053680903760X |
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