[(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide

In the title compound, C(27)H(26)P(2)S, the P—C—P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8),...

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Detalles Bibliográficos
Autores principales: Pitroda, Priyanka P., Badgett, Ansonia H., Dickey, Geralyn A., Gray, Danielle L., Shelby, Quinetta D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970358/
https://www.ncbi.nlm.nih.gov/pubmed/21577779
http://dx.doi.org/10.1107/S1600536809034059
Descripción
Sumario:In the title compound, C(27)H(26)P(2)S, the P—C—P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

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