[(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide

In the title compound, C(27)H(26)P(2)S, the P—C—P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8),...

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Autores principales: Pitroda, Priyanka P., Badgett, Ansonia H., Dickey, Geralyn A., Gray, Danielle L., Shelby, Quinetta D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970358/
https://www.ncbi.nlm.nih.gov/pubmed/21577779
http://dx.doi.org/10.1107/S1600536809034059
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author Pitroda, Priyanka P.
Badgett, Ansonia H.
Dickey, Geralyn A.
Gray, Danielle L.
Shelby, Quinetta D.
author_facet Pitroda, Priyanka P.
Badgett, Ansonia H.
Dickey, Geralyn A.
Gray, Danielle L.
Shelby, Quinetta D.
author_sort Pitroda, Priyanka P.
collection PubMed
description In the title compound, C(27)H(26)P(2)S, the P—C—P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].
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spelling pubmed-29703582010-12-30 [(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide Pitroda, Priyanka P. Badgett, Ansonia H. Dickey, Geralyn A. Gray, Danielle L. Shelby, Quinetta D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(26)P(2)S, the P—C—P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)]. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970358/ /pubmed/21577779 http://dx.doi.org/10.1107/S1600536809034059 Text en © Pitroda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pitroda, Priyanka P.
Badgett, Ansonia H.
Dickey, Geralyn A.
Gray, Danielle L.
Shelby, Quinetta D.
[(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide
title [(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide
title_full [(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide
title_fullStr [(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide
title_full_unstemmed [(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide
title_short [(Di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide
title_sort [(di-o-tolyl­phosphino)meth­yl]diphenyl­phosphine sulfide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970358/
https://www.ncbi.nlm.nih.gov/pubmed/21577779
http://dx.doi.org/10.1107/S1600536809034059
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AT dickeygeralyna diotolylphosphinomethyldiphenylphosphinesulfide
AT graydaniellel diotolylphosphinomethyldiphenylphosphinesulfide
AT shelbyquinettad diotolylphosphinomethyldiphenylphosphinesulfide

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