Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title compound, [CuCl(2)(C(14)H(12)N(2))], the complex molecule has m symmetry, with the mirror plane oriented parallel to the planar molecule and the ligated Cu(II) atom. The metal centre has a distorted tetra­hedral coordination formed by two N atoms from one 2,9-dimethyl-1,10-phenanthrolin...

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Detalles Bibliográficos
Autores principales: Wang, B. S., Zhong, H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970365/
https://www.ncbi.nlm.nih.gov/pubmed/21577696
http://dx.doi.org/10.1107/S1600536809034187
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author Wang, B. S.
Zhong, H.
author_facet Wang, B. S.
Zhong, H.
author_sort Wang, B. S.
collection PubMed
description In the title compound, [CuCl(2)(C(14)H(12)N(2))], the complex molecule has m symmetry, with the mirror plane oriented parallel to the planar molecule and the ligated Cu(II) atom. The metal centre has a distorted tetra­hedral coordination formed by two N atoms from one 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. There is inter­molecular π–π stacking between adjacent 2,9-dimethyl-1,10-phenanthroline ligands, with a centroid–centroid distance of 3.733 (2)Å.
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spelling pubmed-29703652010-12-30 Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II) Wang, B. S. Zhong, H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(14)H(12)N(2))], the complex molecule has m symmetry, with the mirror plane oriented parallel to the planar molecule and the ligated Cu(II) atom. The metal centre has a distorted tetra­hedral coordination formed by two N atoms from one 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. There is inter­molecular π–π stacking between adjacent 2,9-dimethyl-1,10-phenanthroline ligands, with a centroid–centroid distance of 3.733 (2)Å. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970365/ /pubmed/21577696 http://dx.doi.org/10.1107/S1600536809034187 Text en © Wang and Zhong 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, B. S.
Zhong, H.
Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II)
title Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort dichlorido(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970365/
https://www.ncbi.nlm.nih.gov/pubmed/21577696
http://dx.doi.org/10.1107/S1600536809034187
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AT zhongh dichlorido29dimethyl110phenanthrolinek2nncopperii

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