(1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate

The asymmetric unit of the title compound, C(25)H(31)NO(3), prepared from (−)-1R-cis-caronaldehyde, contains three independent mol­ecules with similar conformations. The hydr­oxy groups are involved in intra­molecular O—H⋯N hydrogen bonds. The crystal packing exhibits weak inter­molecular O—H⋯O and...

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Detalles Bibliográficos
Autores principales: Wang, Bo, Ye, Nengsheng, Li, Zhiyuan, Zhong, Jiangchun, Hou, Shicong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970366/
https://www.ncbi.nlm.nih.gov/pubmed/21577926
http://dx.doi.org/10.1107/S1600536809035296
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author Wang, Bo
Ye, Nengsheng
Li, Zhiyuan
Zhong, Jiangchun
Hou, Shicong
author_facet Wang, Bo
Ye, Nengsheng
Li, Zhiyuan
Zhong, Jiangchun
Hou, Shicong
author_sort Wang, Bo
collection PubMed
description The asymmetric unit of the title compound, C(25)H(31)NO(3), prepared from (−)-1R-cis-caronaldehyde, contains three independent mol­ecules with similar conformations. The hydr­oxy groups are involved in intra­molecular O—H⋯N hydrogen bonds. The crystal packing exhibits weak inter­molecular O—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-29703662010-12-30 (1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate Wang, Bo Ye, Nengsheng Li, Zhiyuan Zhong, Jiangchun Hou, Shicong Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(25)H(31)NO(3), prepared from (−)-1R-cis-caronaldehyde, contains three independent mol­ecules with similar conformations. The hydr­oxy groups are involved in intra­molecular O—H⋯N hydrogen bonds. The crystal packing exhibits weak inter­molecular O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2009-09-16 /pmc/articles/PMC2970366/ /pubmed/21577926 http://dx.doi.org/10.1107/S1600536809035296 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Bo
Ye, Nengsheng
Li, Zhiyuan
Zhong, Jiangchun
Hou, Shicong
(1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate
title (1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate
title_full (1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate
title_fullStr (1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate
title_full_unstemmed (1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate
title_short (1R,3S)-Methyl 3-[(S)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate
title_sort (1r,3s)-methyl 3-[(s)-2-(hydroxy­diphenyl­meth­yl)pyrrolidin-1-ylmeth­yl]-2,2-dimethyl­cyclo­propane­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970366/
https://www.ncbi.nlm.nih.gov/pubmed/21577926
http://dx.doi.org/10.1107/S1600536809035296
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