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2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine
In the title compound, C(19)H(24)N(2)O(2)S, the benzodiazepine ring adopts a distorted boat conformation. The S atom shows a distorted tetrahedral geometry, with the O—S—O [119.16 (14)°] and N—S—C [107.48 (10)°] angles deviating significantly from ideal values. The crystal packing is controlled by...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970367/ https://www.ncbi.nlm.nih.gov/pubmed/21577831 http://dx.doi.org/10.1107/S1600536809034837 |
| _version_ | 1782190423746281472 |
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| author | Ravichandran, K. Sathiyaraj, K. Ilango, S. S. Ponnuswamy, S. Ponnuswamy, M. N. |
| author_facet | Ravichandran, K. Sathiyaraj, K. Ilango, S. S. Ponnuswamy, S. Ponnuswamy, M. N. |
| author_sort | Ravichandran, K. |
| collection | PubMed |
| description | In the title compound, C(19)H(24)N(2)O(2)S, the benzodiazepine ring adopts a distorted boat conformation. The S atom shows a distorted tetrahedral geometry, with the O—S—O [119.16 (14)°] and N—S—C [107.48 (10)°] angles deviating significantly from ideal values. The crystal packing is controlled by C—H⋯O, N—H⋯O and C—H⋯π interactions. |
| format | Text |
| id | pubmed-2970367 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29703672010-12-30 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine Ravichandran, K. Sathiyaraj, K. Ilango, S. S. Ponnuswamy, S. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(24)N(2)O(2)S, the benzodiazepine ring adopts a distorted boat conformation. The S atom shows a distorted tetrahedral geometry, with the O—S—O [119.16 (14)°] and N—S—C [107.48 (10)°] angles deviating significantly from ideal values. The crystal packing is controlled by C—H⋯O, N—H⋯O and C—H⋯π interactions. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970367/ /pubmed/21577831 http://dx.doi.org/10.1107/S1600536809034837 Text en © Ravichandran et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Ravichandran, K. Sathiyaraj, K. Ilango, S. S. Ponnuswamy, S. Ponnuswamy, M. N. 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine |
| title | 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine |
| title_full | 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine |
| title_fullStr | 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine |
| title_full_unstemmed | 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine |
| title_short | 2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine |
| title_sort | 2,2,4-trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1h-1,5-benzodiazepine |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970367/ https://www.ncbi.nlm.nih.gov/pubmed/21577831 http://dx.doi.org/10.1107/S1600536809034837 |
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