N,N′-Bis(2-quinolylcarbon­yl)hydrazine

The title compound, C(20)H(14)N(4)O(2), crystallizes in the ortho­rhom­bic system with a crystallographic twofold axis through the N—N bond. The mol­ecule is non-planar and the dihedral angle between two amide groups is 74.9 (2)°. An intra­molecular N—H⋯N hydrogen bond is present. In the crystal, th...

Descripción completa

Detalles Bibliográficos
Autores principales: Cheng, Hui-Min, Chen, Lang, Lu, Wei, Shen, Xuan, Zhu, Dun-Ru
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970370/
https://www.ncbi.nlm.nih.gov/pubmed/21577971
http://dx.doi.org/10.1107/S1600536809037842
_version_ 1782190424590385152
author Cheng, Hui-Min
Chen, Lang
Lu, Wei
Shen, Xuan
Zhu, Dun-Ru
author_facet Cheng, Hui-Min
Chen, Lang
Lu, Wei
Shen, Xuan
Zhu, Dun-Ru
author_sort Cheng, Hui-Min
collection PubMed
description The title compound, C(20)H(14)N(4)O(2), crystallizes in the ortho­rhom­bic system with a crystallographic twofold axis through the N—N bond. The mol­ecule is non-planar and the dihedral angle between two amide groups is 74.9 (2)°. An intra­molecular N—H⋯N hydrogen bond is present. In the crystal, the mol­ecules are packed in chains running along the c axis through inter­molecular N—H⋯O hydrogen bonds. These chains are further stabilized by inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions leading to the formation of a three-dimensional network.
format Text
id pubmed-2970370
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29703702010-12-30 N,N′-Bis(2-quinolylcarbon­yl)hydrazine Cheng, Hui-Min Chen, Lang Lu, Wei Shen, Xuan Zhu, Dun-Ru Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(14)N(4)O(2), crystallizes in the ortho­rhom­bic system with a crystallographic twofold axis through the N—N bond. The mol­ecule is non-planar and the dihedral angle between two amide groups is 74.9 (2)°. An intra­molecular N—H⋯N hydrogen bond is present. In the crystal, the mol­ecules are packed in chains running along the c axis through inter­molecular N—H⋯O hydrogen bonds. These chains are further stabilized by inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions leading to the formation of a three-dimensional network. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970370/ /pubmed/21577971 http://dx.doi.org/10.1107/S1600536809037842 Text en © Cheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Hui-Min
Chen, Lang
Lu, Wei
Shen, Xuan
Zhu, Dun-Ru
N,N′-Bis(2-quinolylcarbon­yl)hydrazine
title N,N′-Bis(2-quinolylcarbon­yl)hydrazine
title_full N,N′-Bis(2-quinolylcarbon­yl)hydrazine
title_fullStr N,N′-Bis(2-quinolylcarbon­yl)hydrazine
title_full_unstemmed N,N′-Bis(2-quinolylcarbon­yl)hydrazine
title_short N,N′-Bis(2-quinolylcarbon­yl)hydrazine
title_sort n,n′-bis(2-quinolylcarbon­yl)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970370/
https://www.ncbi.nlm.nih.gov/pubmed/21577971
http://dx.doi.org/10.1107/S1600536809037842
work_keys_str_mv AT chenghuimin nnbis2quinolylcarbonylhydrazine
AT chenlang nnbis2quinolylcarbonylhydrazine
AT luwei nnbis2quinolylcarbonylhydrazine
AT shenxuan nnbis2quinolylcarbonylhydrazine
AT zhudunru nnbis2quinolylcarbonylhydrazine

Ejemplares similares