Bis(1,3,4-thia­diazol-2-yl) disulfide

The title compound, C(4)H(2)N(4)S(4), lies about a twofold rotation axis situated at the mid-point of the central S—S bond. Each of two thia­diazole rings is essentially planar, with an rms deviation for the unique thia­diazole ring plane of 0.0019 (7) Å. C—H⋯N hydrogen bonds link adjacent mol­ecule...

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Detalles Bibliográficos
Autores principales: Hu, Pu-Zhou, Zhang, Yong-Hua, Wang, Jian-Ge, Qin, Jian-Hua, Zhao, Bang-Tun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970373/
https://www.ncbi.nlm.nih.gov/pubmed/21577934
http://dx.doi.org/10.1107/S1600536809036782
Descripción
Sumario:The title compound, C(4)H(2)N(4)S(4), lies about a twofold rotation axis situated at the mid-point of the central S—S bond. Each of two thia­diazole rings is essentially planar, with an rms deviation for the unique thia­diazole ring plane of 0.0019 (7) Å. C—H⋯N hydrogen bonds link adjacent mol­ecules, forming zigzag chains along the c axis. In addition, these chains are connected by inter­molecular S⋯S inter­actions [S⋯S = 3.5153 (11) Å] , forming corrugated sheets, and further fabricate a three-dimensional supra­molecular structure by inter­molecular N⋯S contacts [S⋯N = 3.1941 (17) Å].

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