Bis(1,3,4-thia­diazol-2-yl) disulfide

The title compound, C(4)H(2)N(4)S(4), lies about a twofold rotation axis situated at the mid-point of the central S—S bond. Each of two thia­diazole rings is essentially planar, with an rms deviation for the unique thia­diazole ring plane of 0.0019 (7) Å. C—H⋯N hydrogen bonds link adjacent mol­ecule...

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Detalles Bibliográficos
Autores principales: Hu, Pu-Zhou, Zhang, Yong-Hua, Wang, Jian-Ge, Qin, Jian-Hua, Zhao, Bang-Tun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970373/
https://www.ncbi.nlm.nih.gov/pubmed/21577934
http://dx.doi.org/10.1107/S1600536809036782
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author Hu, Pu-Zhou
Zhang, Yong-Hua
Wang, Jian-Ge
Qin, Jian-Hua
Zhao, Bang-Tun
author_facet Hu, Pu-Zhou
Zhang, Yong-Hua
Wang, Jian-Ge
Qin, Jian-Hua
Zhao, Bang-Tun
author_sort Hu, Pu-Zhou
collection PubMed
description The title compound, C(4)H(2)N(4)S(4), lies about a twofold rotation axis situated at the mid-point of the central S—S bond. Each of two thia­diazole rings is essentially planar, with an rms deviation for the unique thia­diazole ring plane of 0.0019 (7) Å. C—H⋯N hydrogen bonds link adjacent mol­ecules, forming zigzag chains along the c axis. In addition, these chains are connected by inter­molecular S⋯S inter­actions [S⋯S = 3.5153 (11) Å] , forming corrugated sheets, and further fabricate a three-dimensional supra­molecular structure by inter­molecular N⋯S contacts [S⋯N = 3.1941 (17) Å].
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spelling pubmed-29703732010-12-30 Bis(1,3,4-thia­diazol-2-yl) disulfide Hu, Pu-Zhou Zhang, Yong-Hua Wang, Jian-Ge Qin, Jian-Hua Zhao, Bang-Tun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(4)H(2)N(4)S(4), lies about a twofold rotation axis situated at the mid-point of the central S—S bond. Each of two thia­diazole rings is essentially planar, with an rms deviation for the unique thia­diazole ring plane of 0.0019 (7) Å. C—H⋯N hydrogen bonds link adjacent mol­ecules, forming zigzag chains along the c axis. In addition, these chains are connected by inter­molecular S⋯S inter­actions [S⋯S = 3.5153 (11) Å] , forming corrugated sheets, and further fabricate a three-dimensional supra­molecular structure by inter­molecular N⋯S contacts [S⋯N = 3.1941 (17) Å]. International Union of Crystallography 2009-09-16 /pmc/articles/PMC2970373/ /pubmed/21577934 http://dx.doi.org/10.1107/S1600536809036782 Text en © Hu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Pu-Zhou
Zhang, Yong-Hua
Wang, Jian-Ge
Qin, Jian-Hua
Zhao, Bang-Tun
Bis(1,3,4-thia­diazol-2-yl) disulfide
title Bis(1,3,4-thia­diazol-2-yl) disulfide
title_full Bis(1,3,4-thia­diazol-2-yl) disulfide
title_fullStr Bis(1,3,4-thia­diazol-2-yl) disulfide
title_full_unstemmed Bis(1,3,4-thia­diazol-2-yl) disulfide
title_short Bis(1,3,4-thia­diazol-2-yl) disulfide
title_sort bis(1,3,4-thia­diazol-2-yl) disulfide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970373/
https://www.ncbi.nlm.nih.gov/pubmed/21577934
http://dx.doi.org/10.1107/S1600536809036782
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AT zhangyonghua bis134thiadiazol2yldisulfide
AT wangjiange bis134thiadiazol2yldisulfide
AT qinjianhua bis134thiadiazol2yldisulfide
AT zhaobangtun bis134thiadiazol2yldisulfide

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