Adeninium 3-carboxy­anilinium bis­(perchlorate) trihydrate

In the title salt, C(5)H(6)N(5) (+)·C(7)H(8)NO(2) (+)·2ClO(4) (−)·3H(2)O, the 3-carboxy­anilinium and adeninium cations are monoprotonated at the amino group and at a pyrimidine N atom respectively. In the crystal, the components are involved in extensive three-dimensional hydrogen-bonding networks...

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Detalles Bibliográficos
Autores principales: Bendjeddou, Lamia, Cherouana, Aouatef, Hadjadj, Nasreddine, Dahaoui, Slimane, Lecomte, Claude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970376/
https://www.ncbi.nlm.nih.gov/pubmed/21577777
http://dx.doi.org/10.1107/S1600536809034199
Descripción
Sumario:In the title salt, C(5)H(6)N(5) (+)·C(7)H(8)NO(2) (+)·2ClO(4) (−)·3H(2)O, the 3-carboxy­anilinium and adeninium cations are monoprotonated at the amino group and at a pyrimidine N atom respectively. In the crystal, the components are involved in extensive three-dimensional hydrogen-bonding networks composed of O—H⋯O, N—H⋯O, O—H⋯N, N—H⋯N and C—H⋯O inter­actions. Bifurcated hydrogen bonds are observed between perchlorate O atoms and adeninium cations.

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