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The title compound [systematic name: 1-methoxy-2-(3-methylbut-2-enyl)-9H-carbazole-3-carbaldehyde], C(19)H(19)NO(2), is a natural carbazole which was isolated from the twigs of Clausena lansium. The carbazole ring system is essentially planar with a mean deviation of 0.0068 (10) Å. The aldehyde s...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970378/ https://www.ncbi.nlm.nih.gov/pubmed/21577947 http://dx.doi.org/10.1107/S1600536809036915 |
Sumario: | The title compound [systematic name: 1-methoxy-2-(3-methylbut-2-enyl)-9H-carbazole-3-carbaldehyde], C(19)H(19)NO(2), is a natural carbazole which was isolated from the twigs of Clausena lansium. The carbazole ring system is essentially planar with a mean deviation of 0.0068 (10) Å. The aldehyde substituent is approximately co-planar with the attached benzene ring with a torsion angle of −8.58 (14)°, whereas the methoxy group is rotated out of the benzene plane with a torsion angle of −82.17 (11)°. The dihedral angle between the mean planes of the 3-methyl-2-butenyl group and the carbazole ring is 88.06 (5)°. An intermolecular N—H⋯O interaction connects the molecules into a chain along the a axis. The crystal is further consolidated by a C—H⋯O hydrogen bond and two π–π interactions with centroid–centroid distances of 3.6592 (6) and 3.7440 (6) Å. |
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