(2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate

Colourless crystals of the title compound, [Ag(C(5)H(7)N(3))(C(6)H(9)N(3))]NO(3), separated out of a solution of 2-amino-4-methyl­pyrimidine, 2-amino-4,6-dimethyl­pyrimidine and silver nitrate in water and methanol. The central Ag(I) ion is coordinated by two different N atoms in the aromatic rings...

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Detalles Bibliográficos
Autor principal: Yang, Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970381/
https://www.ncbi.nlm.nih.gov/pubmed/21577712
http://dx.doi.org/10.1107/S1600536809035181
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author Yang, Hua
author_facet Yang, Hua
author_sort Yang, Hua
collection PubMed
description Colourless crystals of the title compound, [Ag(C(5)H(7)N(3))(C(6)H(9)N(3))]NO(3), separated out of a solution of 2-amino-4-methyl­pyrimidine, 2-amino-4,6-dimethyl­pyrimidine and silver nitrate in water and methanol. The central Ag(I) ion is coordinated by two different N atoms in the aromatic rings of the ligands, with an N—Ag—N angle of 173.9 (2)°. The crystal structure is composed of two complexed cations and stabilized by an inter­molecular N—H⋯O and N—H⋯N hydrogen-bond network and there is π–π stacking of the aromatic rings [inter­planar distance 3.651 (10) Å].
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spelling pubmed-29703812010-12-30 (2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate Yang, Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Colourless crystals of the title compound, [Ag(C(5)H(7)N(3))(C(6)H(9)N(3))]NO(3), separated out of a solution of 2-amino-4-methyl­pyrimidine, 2-amino-4,6-dimethyl­pyrimidine and silver nitrate in water and methanol. The central Ag(I) ion is coordinated by two different N atoms in the aromatic rings of the ligands, with an N—Ag—N angle of 173.9 (2)°. The crystal structure is composed of two complexed cations and stabilized by an inter­molecular N—H⋯O and N—H⋯N hydrogen-bond network and there is π–π stacking of the aromatic rings [inter­planar distance 3.651 (10) Å]. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970381/ /pubmed/21577712 http://dx.doi.org/10.1107/S1600536809035181 Text en © Hua Yang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Hua
(2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate
title (2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate
title_full (2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate
title_fullStr (2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate
title_full_unstemmed (2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate
title_short (2-Amino-4,6-dimethyl­pyrimidine-κN (1))(2-amino-4-methyl­pyrimidine-κN (1))silver(I) nitrate
title_sort (2-amino-4,6-dimethyl­pyrimidine-κn (1))(2-amino-4-methyl­pyrimidine-κn (1))silver(i) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970381/
https://www.ncbi.nlm.nih.gov/pubmed/21577712
http://dx.doi.org/10.1107/S1600536809035181
work_keys_str_mv AT yanghua 2amino46dimethylpyrimidinekn12amino4methylpyrimidinekn1silverinitrate

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