1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate

The bonds in the five-membered ring of the title hydrated salt, C(14)H(17)N(2) (+)·Br(−)·2H(2)O, are delocalized. The cation lies on a special position of m site symmetry such that the mirror plane passes through the imidazol­yl–methyl bond and is perpendicular to the plane of the cation. The anion...

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Autores principales: Ennajih, Hamid, Bouhfid, Rachid, Zouihri, Hafid, Essassi, El Mokhtar, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970382/
https://www.ncbi.nlm.nih.gov/pubmed/21577792
http://dx.doi.org/10.1107/S1600536809034175
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author Ennajih, Hamid
Bouhfid, Rachid
Zouihri, Hafid
Essassi, El Mokhtar
Ng, Seik Weng
author_facet Ennajih, Hamid
Bouhfid, Rachid
Zouihri, Hafid
Essassi, El Mokhtar
Ng, Seik Weng
author_sort Ennajih, Hamid
collection PubMed
description The bonds in the five-membered ring of the title hydrated salt, C(14)H(17)N(2) (+)·Br(−)·2H(2)O, are delocalized. The cation lies on a special position of m site symmetry such that the mirror plane passes through the imidazol­yl–methyl bond and is perpendicular to the plane of the cation. The anion lies on another special position of 2 site symmetry. The anion and uncoordinated water mol­ecule are linked into a chain by O—H⋯O hydrogen bonds. One of the water O atoms is disordered over two sites of equal occupancy.
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spelling pubmed-29703822010-12-30 1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate Ennajih, Hamid Bouhfid, Rachid Zouihri, Hafid Essassi, El Mokhtar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The bonds in the five-membered ring of the title hydrated salt, C(14)H(17)N(2) (+)·Br(−)·2H(2)O, are delocalized. The cation lies on a special position of m site symmetry such that the mirror plane passes through the imidazol­yl–methyl bond and is perpendicular to the plane of the cation. The anion lies on another special position of 2 site symmetry. The anion and uncoordinated water mol­ecule are linked into a chain by O—H⋯O hydrogen bonds. One of the water O atoms is disordered over two sites of equal occupancy. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970382/ /pubmed/21577792 http://dx.doi.org/10.1107/S1600536809034175 Text en © Ennajih et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ennajih, Hamid
Bouhfid, Rachid
Zouihri, Hafid
Essassi, El Mokhtar
Ng, Seik Weng
1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate
title 1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate
title_full 1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate
title_fullStr 1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate
title_full_unstemmed 1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate
title_short 1,3-Diallyl-2-methyl­benzimidazolium bromide dihydrate
title_sort 1,3-diallyl-2-methyl­benzimidazolium bromide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970382/
https://www.ncbi.nlm.nih.gov/pubmed/21577792
http://dx.doi.org/10.1107/S1600536809034175
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AT essassielmokhtar 13diallyl2methylbenzimidazoliumbromidedihydrate
AT ngseikweng 13diallyl2methylbenzimidazoliumbromidedihydrate

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