A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol

The title chiral photochromic Schiff base compound, C(16)H(17)NO(2), was synthesized from (R)-1-phenyl­ethyl­amine and 5-methoxy­salicylaldehyde. The mol­ecule of the title compound exists in the phenol–imine tautomeric form. The dihedral angle between the two aromatic rings is 62.61 (11)°. An intra...

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Detalles Bibliográficos
Autores principales: Miura, Yukie, Aritake, Yoshikazu, Akitsu, Takashiro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970391/
https://www.ncbi.nlm.nih.gov/pubmed/21577845
http://dx.doi.org/10.1107/S1600536809035557
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author Miura, Yukie
Aritake, Yoshikazu
Akitsu, Takashiro
author_facet Miura, Yukie
Aritake, Yoshikazu
Akitsu, Takashiro
author_sort Miura, Yukie
collection PubMed
description The title chiral photochromic Schiff base compound, C(16)H(17)NO(2), was synthesized from (R)-1-phenyl­ethyl­amine and 5-methoxy­salicylaldehyde. The mol­ecule of the title compound exists in the phenol–imine tautomeric form. The dihedral angle between the two aromatic rings is 62.61 (11)°. An intra­molecular O—H⋯N hydrogen bond with an O⋯N distance of 2.589 (2) Å is observed. The crystal packing is stabilized by C—H⋯π inter­actions involving the aromatic ring.
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spelling pubmed-29703912010-12-30 A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol Miura, Yukie Aritake, Yoshikazu Akitsu, Takashiro Acta Crystallogr Sect E Struct Rep Online Organic Papers The title chiral photochromic Schiff base compound, C(16)H(17)NO(2), was synthesized from (R)-1-phenyl­ethyl­amine and 5-methoxy­salicylaldehyde. The mol­ecule of the title compound exists in the phenol–imine tautomeric form. The dihedral angle between the two aromatic rings is 62.61 (11)°. An intra­molecular O—H⋯N hydrogen bond with an O⋯N distance of 2.589 (2) Å is observed. The crystal packing is stabilized by C—H⋯π inter­actions involving the aromatic ring. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970391/ /pubmed/21577845 http://dx.doi.org/10.1107/S1600536809035557 Text en © Miura et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Miura, Yukie
Aritake, Yoshikazu
Akitsu, Takashiro
A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol
title A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol
title_full A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol
title_fullStr A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol
title_full_unstemmed A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol
title_short A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol
title_sort chiral photochromic schiff base: (r)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970391/
https://www.ncbi.nlm.nih.gov/pubmed/21577845
http://dx.doi.org/10.1107/S1600536809035557
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