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1,3-Bis(2-ethoxyphenyl)triazene methanol 0.33-solvate
There are three independent molecules of 1,3-bis(2-ethoxyphenyl)triazene and a molecule of methanol in the asymmetric unit of the title compound, C(16)H(19)N(3)O(2)·0.33CH(3)OH. Two molecules related by a non-crystallographic pseudo-twofold rotation axis are linked via distinct intermolecular...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970393/ https://www.ncbi.nlm.nih.gov/pubmed/21577855 http://dx.doi.org/10.1107/S1600536809035338 |
Sumario: | There are three independent molecules of 1,3-bis(2-ethoxyphenyl)triazene and a molecule of methanol in the asymmetric unit of the title compound, C(16)H(19)N(3)O(2)·0.33CH(3)OH. Two molecules related by a non-crystallographic pseudo-twofold rotation axis are linked via distinct intermolecular N—H⋯N hydrogen bonds, leading to the formation of a dimer with an R (2) (2)(8) graph set. The third molecule is connected to the methanol molecule by O—H⋯N and N—H⋯O hydrogen bonds. There are a number of weak C—H⋯π interactions, with H⋯π distances ranging from 2.74 to 2.89 Å between the C—H groups and the aromatic benzene rings. |
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