Cargando…

1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate

There are three independent mol­ecules of 1,3-bis­(2-ethoxy­phen­yl)triazene and a mol­ecule of methanol in the asymmetric unit of the title compound, C(16)H(19)N(3)O(2)·0.33CH(3)OH. Two mol­ecules related by a non-crystallographic pseudo-twofold rotation axis are linked via distinct inter­molecular...

Descripción completa

Detalles Bibliográficos
Autores principales: Rofouei, Mohammad Kazem, Melardi, Mohammad Reza, Salemi, Yasaman, Attar Gharamaleki, Jafar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970393/
https://www.ncbi.nlm.nih.gov/pubmed/21577855
http://dx.doi.org/10.1107/S1600536809035338
_version_ 1782190431130353664
author Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Salemi, Yasaman
Attar Gharamaleki, Jafar
author_facet Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Salemi, Yasaman
Attar Gharamaleki, Jafar
author_sort Rofouei, Mohammad Kazem
collection PubMed
description There are three independent mol­ecules of 1,3-bis­(2-ethoxy­phen­yl)triazene and a mol­ecule of methanol in the asymmetric unit of the title compound, C(16)H(19)N(3)O(2)·0.33CH(3)OH. Two mol­ecules related by a non-crystallographic pseudo-twofold rotation axis are linked via distinct inter­molecular N—H⋯N hydrogen bonds, leading to the formation of a dimer with an R (2) (2)(8) graph set. The third mol­ecule is connected to the methanol mol­ecule by O—H⋯N and N—H⋯O hydrogen bonds. There are a number of weak C—H⋯π inter­actions, with H⋯π distances ranging from 2.74 to 2.89 Å between the C—H groups and the aromatic benzene rings.
format Text
id pubmed-2970393
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29703932010-12-30 1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate Rofouei, Mohammad Kazem Melardi, Mohammad Reza Salemi, Yasaman Attar Gharamaleki, Jafar Acta Crystallogr Sect E Struct Rep Online Organic Papers There are three independent mol­ecules of 1,3-bis­(2-ethoxy­phen­yl)triazene and a mol­ecule of methanol in the asymmetric unit of the title compound, C(16)H(19)N(3)O(2)·0.33CH(3)OH. Two mol­ecules related by a non-crystallographic pseudo-twofold rotation axis are linked via distinct inter­molecular N—H⋯N hydrogen bonds, leading to the formation of a dimer with an R (2) (2)(8) graph set. The third mol­ecule is connected to the methanol mol­ecule by O—H⋯N and N—H⋯O hydrogen bonds. There are a number of weak C—H⋯π inter­actions, with H⋯π distances ranging from 2.74 to 2.89 Å between the C—H groups and the aromatic benzene rings. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970393/ /pubmed/21577855 http://dx.doi.org/10.1107/S1600536809035338 Text en © Rofouei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Salemi, Yasaman
Attar Gharamaleki, Jafar
1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate
title 1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate
title_full 1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate
title_fullStr 1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate
title_full_unstemmed 1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate
title_short 1,3-Bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate
title_sort 1,3-bis(2-ethoxy­phen­yl)triazene methanol 0.33-solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970393/
https://www.ncbi.nlm.nih.gov/pubmed/21577855
http://dx.doi.org/10.1107/S1600536809035338
work_keys_str_mv AT rofoueimohammadkazem 13bis2ethoxyphenyltriazenemethanol033solvate
AT melardimohammadreza 13bis2ethoxyphenyltriazenemethanol033solvate
AT salemiyasaman 13bis2ethoxyphenyltriazenemethanol033solvate
AT attargharamalekijafar 13bis2ethoxyphenyltriazenemethanol033solvate