1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine

The mol­ecule of the title Schiff base compound, C(10)H(11)N(3)O(2), adopts an E geometry with respect to the C=N double bond. The mol­ecule is roughly planar, with the largest deviation from the mean plane being 0.111 (2) Å, The enyl­idene-hydrazine group is, however, slightly twisted with respect...

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Detalles Bibliográficos
Autores principales: Yin, Zhi-Gang, Qian, Heng-Yu, Zhu, Xue-Wen, Zhang, Chun-Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970396/
https://www.ncbi.nlm.nih.gov/pubmed/21577941
http://dx.doi.org/10.1107/S1600536809037179
Descripción
Sumario:The mol­ecule of the title Schiff base compound, C(10)H(11)N(3)O(2), adopts an E geometry with respect to the C=N double bond. The mol­ecule is roughly planar, with the largest deviation from the mean plane being 0.111 (2) Å, The enyl­idene-hydrazine group is, however, slightly twisted with respect to the phenyl ring, making a dihedral angle of 6.5 (3)°. An intra­molecular N—H⋯O hydrogen bond may be responsible for the planar conformation. An inter­molecular N—H⋯O hydrogen bond links two mol­ecules around an inversion center, building a pseudo dimer.

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