1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine

The mol­ecule of the title Schiff base compound, C(10)H(11)N(3)O(2), adopts an E geometry with respect to the C=N double bond. The mol­ecule is roughly planar, with the largest deviation from the mean plane being 0.111 (2) Å, The enyl­idene-hydrazine group is, however, slightly twisted with respect...

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Detalles Bibliográficos
Autores principales: Yin, Zhi-Gang, Qian, Heng-Yu, Zhu, Xue-Wen, Zhang, Chun-Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970396/
https://www.ncbi.nlm.nih.gov/pubmed/21577941
http://dx.doi.org/10.1107/S1600536809037179
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author Yin, Zhi-Gang
Qian, Heng-Yu
Zhu, Xue-Wen
Zhang, Chun-Xia
author_facet Yin, Zhi-Gang
Qian, Heng-Yu
Zhu, Xue-Wen
Zhang, Chun-Xia
author_sort Yin, Zhi-Gang
collection PubMed
description The mol­ecule of the title Schiff base compound, C(10)H(11)N(3)O(2), adopts an E geometry with respect to the C=N double bond. The mol­ecule is roughly planar, with the largest deviation from the mean plane being 0.111 (2) Å, The enyl­idene-hydrazine group is, however, slightly twisted with respect to the phenyl ring, making a dihedral angle of 6.5 (3)°. An intra­molecular N—H⋯O hydrogen bond may be responsible for the planar conformation. An inter­molecular N—H⋯O hydrogen bond links two mol­ecules around an inversion center, building a pseudo dimer.
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spelling pubmed-29703962010-12-30 1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine Yin, Zhi-Gang Qian, Heng-Yu Zhu, Xue-Wen Zhang, Chun-Xia Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title Schiff base compound, C(10)H(11)N(3)O(2), adopts an E geometry with respect to the C=N double bond. The mol­ecule is roughly planar, with the largest deviation from the mean plane being 0.111 (2) Å, The enyl­idene-hydrazine group is, however, slightly twisted with respect to the phenyl ring, making a dihedral angle of 6.5 (3)°. An intra­molecular N—H⋯O hydrogen bond may be responsible for the planar conformation. An inter­molecular N—H⋯O hydrogen bond links two mol­ecules around an inversion center, building a pseudo dimer. International Union of Crystallography 2009-09-19 /pmc/articles/PMC2970396/ /pubmed/21577941 http://dx.doi.org/10.1107/S1600536809037179 Text en © Yin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yin, Zhi-Gang
Qian, Heng-Yu
Zhu, Xue-Wen
Zhang, Chun-Xia
1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine
title 1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine
title_full 1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine
title_fullStr 1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine
title_full_unstemmed 1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine
title_short 1-(But-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine
title_sort 1-(but-2-enyl­idene)-2-(2-nitro­phen­yl)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970396/
https://www.ncbi.nlm.nih.gov/pubmed/21577941
http://dx.doi.org/10.1107/S1600536809037179
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