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Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)

In the title compound, [Ni(C(8)H(7)O(3))(NO(3))(C(12)H(12)N(2))(2)], the asymmetric unit contains a Ni(II) atom, two mol­ecules of 2-(benzyl­amino)pyridine, a mol­ecule of deprotonated o-vanillin (3-methoxy­salicylaldehydate) and a bidentate nitrate anion. The Ni(II) center is six-coordinated by two...

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Detalles Bibliográficos
Autores principales: Butcher, Ray J., Gultneh, Yilma, Ayikoé, Kouassi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970399/
https://www.ncbi.nlm.nih.gov/pubmed/21577724
http://dx.doi.org/10.1107/S1600536809035570
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author Butcher, Ray J.
Gultneh, Yilma
Ayikoé, Kouassi
author_facet Butcher, Ray J.
Gultneh, Yilma
Ayikoé, Kouassi
author_sort Butcher, Ray J.
collection PubMed
description In the title compound, [Ni(C(8)H(7)O(3))(NO(3))(C(12)H(12)N(2))(2)], the asymmetric unit contains a Ni(II) atom, two mol­ecules of 2-(benzyl­amino)pyridine, a mol­ecule of deprotonated o-vanillin (3-methoxy­salicylaldehydate) and a bidentate nitrate anion. The Ni(II) center is six-coordinated by two pyridine N atoms from 2-(benzyl­amino)pyridine, two O atoms from o-vanillin and two O atoms from the nitrate anion. The crystal packing shows two hydrogen bonds from the amine N—H group to the deprotonated phenol O atom of the o-vanillin moieties, as well as weak C—H⋯O secondary inter­actions. These inter­actions link the mol­ecules into ribbons in the c direction. The steric requirement of the bidentate nitrate and its small bite angle [61.01 (3)°] cause some orientation of the two 2-(benzyl­amino)pyridine groups. As a result, this coordination environment of the Ni(II) center is distorted octa­hedral, as the trans angles range from 158.65 (3) to 175.76 (3)° and the cis angles range from 61.01 (3) (for the bidentate nitrate O atoms) to 102.30 (4)°.
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spelling pubmed-29703992010-12-30 Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II) Butcher, Ray J. Gultneh, Yilma Ayikoé, Kouassi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(7)O(3))(NO(3))(C(12)H(12)N(2))(2)], the asymmetric unit contains a Ni(II) atom, two mol­ecules of 2-(benzyl­amino)pyridine, a mol­ecule of deprotonated o-vanillin (3-methoxy­salicylaldehydate) and a bidentate nitrate anion. The Ni(II) center is six-coordinated by two pyridine N atoms from 2-(benzyl­amino)pyridine, two O atoms from o-vanillin and two O atoms from the nitrate anion. The crystal packing shows two hydrogen bonds from the amine N—H group to the deprotonated phenol O atom of the o-vanillin moieties, as well as weak C—H⋯O secondary inter­actions. These inter­actions link the mol­ecules into ribbons in the c direction. The steric requirement of the bidentate nitrate and its small bite angle [61.01 (3)°] cause some orientation of the two 2-(benzyl­amino)pyridine groups. As a result, this coordination environment of the Ni(II) center is distorted octa­hedral, as the trans angles range from 158.65 (3) to 175.76 (3)° and the cis angles range from 61.01 (3) (for the bidentate nitrate O atoms) to 102.30 (4)°. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970399/ /pubmed/21577724 http://dx.doi.org/10.1107/S1600536809035570 Text en © Butcher et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Butcher, Ray J.
Gultneh, Yilma
Ayikoé, Kouassi
Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)
title Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)
title_full Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)
title_fullStr Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)
title_full_unstemmed Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)
title_short Bis[2-(benzyl­amino)pyridine-κN](2-formyl-6-methoxy­phenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)
title_sort bis[2-(benzyl­amino)pyridine-κn](2-formyl-6-methoxy­phenolato-κ(2) o (1),o (6))(nitrato-κ(2) o,o′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970399/
https://www.ncbi.nlm.nih.gov/pubmed/21577724
http://dx.doi.org/10.1107/S1600536809035570
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