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Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II)
In the title compound, [Ni(C(8)H(7)O(3))(NO(3))(C(12)H(12)N(2))(2)], the asymmetric unit contains a Ni(II) atom, two molecules of 2-(benzylamino)pyridine, a molecule of deprotonated o-vanillin (3-methoxysalicylaldehydate) and a bidentate nitrate anion. The Ni(II) center is six-coordinated by two...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970399/ https://www.ncbi.nlm.nih.gov/pubmed/21577724 http://dx.doi.org/10.1107/S1600536809035570 |
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author | Butcher, Ray J. Gultneh, Yilma Ayikoé, Kouassi |
author_facet | Butcher, Ray J. Gultneh, Yilma Ayikoé, Kouassi |
author_sort | Butcher, Ray J. |
collection | PubMed |
description | In the title compound, [Ni(C(8)H(7)O(3))(NO(3))(C(12)H(12)N(2))(2)], the asymmetric unit contains a Ni(II) atom, two molecules of 2-(benzylamino)pyridine, a molecule of deprotonated o-vanillin (3-methoxysalicylaldehydate) and a bidentate nitrate anion. The Ni(II) center is six-coordinated by two pyridine N atoms from 2-(benzylamino)pyridine, two O atoms from o-vanillin and two O atoms from the nitrate anion. The crystal packing shows two hydrogen bonds from the amine N—H group to the deprotonated phenol O atom of the o-vanillin moieties, as well as weak C—H⋯O secondary interactions. These interactions link the molecules into ribbons in the c direction. The steric requirement of the bidentate nitrate and its small bite angle [61.01 (3)°] cause some orientation of the two 2-(benzylamino)pyridine groups. As a result, this coordination environment of the Ni(II) center is distorted octahedral, as the trans angles range from 158.65 (3) to 175.76 (3)° and the cis angles range from 61.01 (3) (for the bidentate nitrate O atoms) to 102.30 (4)°. |
format | Text |
id | pubmed-2970399 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29703992010-12-30 Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II) Butcher, Ray J. Gultneh, Yilma Ayikoé, Kouassi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(7)O(3))(NO(3))(C(12)H(12)N(2))(2)], the asymmetric unit contains a Ni(II) atom, two molecules of 2-(benzylamino)pyridine, a molecule of deprotonated o-vanillin (3-methoxysalicylaldehydate) and a bidentate nitrate anion. The Ni(II) center is six-coordinated by two pyridine N atoms from 2-(benzylamino)pyridine, two O atoms from o-vanillin and two O atoms from the nitrate anion. The crystal packing shows two hydrogen bonds from the amine N—H group to the deprotonated phenol O atom of the o-vanillin moieties, as well as weak C—H⋯O secondary interactions. These interactions link the molecules into ribbons in the c direction. The steric requirement of the bidentate nitrate and its small bite angle [61.01 (3)°] cause some orientation of the two 2-(benzylamino)pyridine groups. As a result, this coordination environment of the Ni(II) center is distorted octahedral, as the trans angles range from 158.65 (3) to 175.76 (3)° and the cis angles range from 61.01 (3) (for the bidentate nitrate O atoms) to 102.30 (4)°. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970399/ /pubmed/21577724 http://dx.doi.org/10.1107/S1600536809035570 Text en © Butcher et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Butcher, Ray J. Gultneh, Yilma Ayikoé, Kouassi Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2) O (1),O (6))(nitrato-κ(2) O,O′)nickel(II) |
title | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2)
O
(1),O
(6))(nitrato-κ(2)
O,O′)nickel(II) |
title_full | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2)
O
(1),O
(6))(nitrato-κ(2)
O,O′)nickel(II) |
title_fullStr | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2)
O
(1),O
(6))(nitrato-κ(2)
O,O′)nickel(II) |
title_full_unstemmed | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2)
O
(1),O
(6))(nitrato-κ(2)
O,O′)nickel(II) |
title_short | Bis[2-(benzylamino)pyridine-κN](2-formyl-6-methoxyphenolato-κ(2)
O
(1),O
(6))(nitrato-κ(2)
O,O′)nickel(II) |
title_sort | bis[2-(benzylamino)pyridine-κn](2-formyl-6-methoxyphenolato-κ(2)
o
(1),o
(6))(nitrato-κ(2)
o,o′)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970399/ https://www.ncbi.nlm.nih.gov/pubmed/21577724 http://dx.doi.org/10.1107/S1600536809035570 |
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