Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide

In the title dinuclear iridium(III) complex, [Ir(2)(C(10)H(15))(2)(C(5)H(5)N(2)S)(2)]I(2), the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1−) [(2-py)SNH] ligands in a μ-(2-py)SNH-κ(2) N(py),N(NH):κN(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center,...

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Detalles Bibliográficos
Autores principales: Sekioka, Yusuke, Suzuki, Takayoshi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970401/
https://www.ncbi.nlm.nih.gov/pubmed/21577749
http://dx.doi.org/10.1107/S1600536809037167
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author Sekioka, Yusuke
Suzuki, Takayoshi
author_facet Sekioka, Yusuke
Suzuki, Takayoshi
author_sort Sekioka, Yusuke
collection PubMed
description In the title dinuclear iridium(III) complex, [Ir(2)(C(10)H(15))(2)(C(5)H(5)N(2)S)(2)]I(2), the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1−) [(2-py)SNH] ligands in a μ-(2-py)SNH-κ(2) N(py),N(NH):κN(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center, resulting in a planar Ir(2)N(2) ring with an Ir—N(py) bond length of 2.085 (9) Å and bridging Ir—N(NH) bonds of 2.110 (9) and 2.113 (9) Å. The two (2-py)S units have mutually anti configurations with respect to the Ir(2)N(2) ring
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spelling pubmed-29704012010-12-30 Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide Sekioka, Yusuke Suzuki, Takayoshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear iridium(III) complex, [Ir(2)(C(10)H(15))(2)(C(5)H(5)N(2)S)(2)]I(2), the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1−) [(2-py)SNH] ligands in a μ-(2-py)SNH-κ(2) N(py),N(NH):κN(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center, resulting in a planar Ir(2)N(2) ring with an Ir—N(py) bond length of 2.085 (9) Å and bridging Ir—N(NH) bonds of 2.110 (9) and 2.113 (9) Å. The two (2-py)S units have mutually anti configurations with respect to the Ir(2)N(2) ring International Union of Crystallography 2009-09-19 /pmc/articles/PMC2970401/ /pubmed/21577749 http://dx.doi.org/10.1107/S1600536809037167 Text en © Sekioka and Suzuki 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sekioka, Yusuke
Suzuki, Takayoshi
Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide
title Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide
title_full Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide
title_fullStr Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide
title_full_unstemmed Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide
title_short Bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(III)] diiodide
title_sort bis[μ-2-(aminosulfanyl)pyridine(1−)]bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)iridium(iii)] diiodide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970401/
https://www.ncbi.nlm.nih.gov/pubmed/21577749
http://dx.doi.org/10.1107/S1600536809037167
work_keys_str_mv AT sekiokayusuke bism2aminosulfanylpyridine1bisē5pentamethylcyclopentadienyliridiumiiidiiodide
AT suzukitakayoshi bism2aminosulfanylpyridine1bisē5pentamethylcyclopentadienyliridiumiiidiiodide

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