2,4-Dichloro-N-p-tolyl­benzamide

In the title compound, C(14)H(11)Cl(2)NO, the C—N—C(=O)—C amide unit is almost planar (r.m.s. deviation = 0.0317 Å) and subtends dihedral angles of 65.93 (6) and 29.45 (7)°, respectively, to the dichloro­benzene and tolyl rings. The two aromatic rings are inclined at 37.92 (6)° to one another. In th...

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Detalles Bibliográficos
Autores principales: Saeed, Aamer, Khera, Rasheed Ahmad, Rafique, Hummera, Simpson, Jim, Stanley, Roderick G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970402/
https://www.ncbi.nlm.nih.gov/pubmed/21577972
http://dx.doi.org/10.1107/S1600536809034710
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author Saeed, Aamer
Khera, Rasheed Ahmad
Rafique, Hummera
Simpson, Jim
Stanley, Roderick G.
author_facet Saeed, Aamer
Khera, Rasheed Ahmad
Rafique, Hummera
Simpson, Jim
Stanley, Roderick G.
author_sort Saeed, Aamer
collection PubMed
description In the title compound, C(14)H(11)Cl(2)NO, the C—N—C(=O)—C amide unit is almost planar (r.m.s. deviation = 0.0317 Å) and subtends dihedral angles of 65.93 (6) and 29.45 (7)°, respectively, to the dichloro­benzene and tolyl rings. The two aromatic rings are inclined at 37.92 (6)° to one another. In the crystal structure, N—H⋯O hydrogen bonds link the mol­ecules into chains along b. Additional weak C—H⋯Cl and C—H⋯O hydrogen bonds combine with C—H⋯π and very weak π–π contacts [Cg⋯Cg distance = 4.0217 (12) Å] to stack the mol­ecules down b.
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spelling pubmed-29704022010-12-30 2,4-Dichloro-N-p-tolyl­benzamide Saeed, Aamer Khera, Rasheed Ahmad Rafique, Hummera Simpson, Jim Stanley, Roderick G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(11)Cl(2)NO, the C—N—C(=O)—C amide unit is almost planar (r.m.s. deviation = 0.0317 Å) and subtends dihedral angles of 65.93 (6) and 29.45 (7)°, respectively, to the dichloro­benzene and tolyl rings. The two aromatic rings are inclined at 37.92 (6)° to one another. In the crystal structure, N—H⋯O hydrogen bonds link the mol­ecules into chains along b. Additional weak C—H⋯Cl and C—H⋯O hydrogen bonds combine with C—H⋯π and very weak π–π contacts [Cg⋯Cg distance = 4.0217 (12) Å] to stack the mol­ecules down b. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970402/ /pubmed/21577972 http://dx.doi.org/10.1107/S1600536809034710 Text en © Saeed et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Aamer
Khera, Rasheed Ahmad
Rafique, Hummera
Simpson, Jim
Stanley, Roderick G.
2,4-Dichloro-N-p-tolyl­benzamide
title 2,4-Dichloro-N-p-tolyl­benzamide
title_full 2,4-Dichloro-N-p-tolyl­benzamide
title_fullStr 2,4-Dichloro-N-p-tolyl­benzamide
title_full_unstemmed 2,4-Dichloro-N-p-tolyl­benzamide
title_short 2,4-Dichloro-N-p-tolyl­benzamide
title_sort 2,4-dichloro-n-p-tolyl­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970402/
https://www.ncbi.nlm.nih.gov/pubmed/21577972
http://dx.doi.org/10.1107/S1600536809034710
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AT stanleyroderickg 24dichloronptolylbenzamide

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