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[1,3-Bis(2-ethoxyphenyl)triazenido]bromidomercury(II)
To the central atom of the title compound, [HgBr(C(16)H(18)N(3)O(2))], is attached one bromide ion and a 1,3-bis(2-ethoxyphenyl)triazenide ligand through one O and two N atoms, forming a distorted square-planar geometry around the Hg(II) atom. The mononuclear complexes are linked into centrosymme...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970410/ https://www.ncbi.nlm.nih.gov/pubmed/21577772 http://dx.doi.org/10.1107/S1600536809038732 |
Sumario: | To the central atom of the title compound, [HgBr(C(16)H(18)N(3)O(2))], is attached one bromide ion and a 1,3-bis(2-ethoxyphenyl)triazenide ligand through one O and two N atoms, forming a distorted square-planar geometry around the Hg(II) atom. The mononuclear complexes are linked into centrosymmetric dimers by non-classical intermolecular C—H⋯N hydrogen bonds and by weak Hg–η(3)-arene π-interactions [mean distance = 3.434 (3) Å]. The resulting dimeric units are assembled into zigzag chains by translation along the crystallographic c axis through secondary C—H⋯π edge-to-face benzene ring interactions. |
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