[1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II)

To the central atom of the title compound, [HgBr(C(16)H(18)N(3)O(2))], is attached one bromide ion and a 1,3-bis­(2-ethoxy­phen­yl)triazenide ligand through one O and two N atoms, forming a distorted square-planar geometry around the Hg(II) atom. The mononuclear complexes are linked into centrosymme...

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Detalles Bibliográficos
Autores principales: Rofouei, Mohammad Kazem, Beiza, Armin, Attar Gharamaleki, Jafar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970410/
https://www.ncbi.nlm.nih.gov/pubmed/21577772
http://dx.doi.org/10.1107/S1600536809038732
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author Rofouei, Mohammad Kazem
Beiza, Armin
Attar Gharamaleki, Jafar
author_facet Rofouei, Mohammad Kazem
Beiza, Armin
Attar Gharamaleki, Jafar
author_sort Rofouei, Mohammad Kazem
collection PubMed
description To the central atom of the title compound, [HgBr(C(16)H(18)N(3)O(2))], is attached one bromide ion and a 1,3-bis­(2-ethoxy­phen­yl)triazenide ligand through one O and two N atoms, forming a distorted square-planar geometry around the Hg(II) atom. The mononuclear complexes are linked into centrosymmetric dimers by non-classical inter­molecular C—H⋯N hydrogen bonds and by weak Hg–η(3)-arene π-inter­actions [mean distance = 3.434 (3) Å]. The resulting dimeric units are assembled into zigzag chains by translation along the crystallographic c axis through secondary C—H⋯π edge-to-face benzene ring inter­actions.
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spelling pubmed-29704102010-12-30 [1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II) Rofouei, Mohammad Kazem Beiza, Armin Attar Gharamaleki, Jafar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers To the central atom of the title compound, [HgBr(C(16)H(18)N(3)O(2))], is attached one bromide ion and a 1,3-bis­(2-ethoxy­phen­yl)triazenide ligand through one O and two N atoms, forming a distorted square-planar geometry around the Hg(II) atom. The mononuclear complexes are linked into centrosymmetric dimers by non-classical inter­molecular C—H⋯N hydrogen bonds and by weak Hg–η(3)-arene π-inter­actions [mean distance = 3.434 (3) Å]. The resulting dimeric units are assembled into zigzag chains by translation along the crystallographic c axis through secondary C—H⋯π edge-to-face benzene ring inter­actions. International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970410/ /pubmed/21577772 http://dx.doi.org/10.1107/S1600536809038732 Text en © Rofouei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rofouei, Mohammad Kazem
Beiza, Armin
Attar Gharamaleki, Jafar
[1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II)
title [1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II)
title_full [1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II)
title_fullStr [1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II)
title_full_unstemmed [1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II)
title_short [1,3-Bis(2-ethoxy­phen­yl)triazenido]bromidomercury(II)
title_sort [1,3-bis(2-ethoxy­phen­yl)triazenido]bromidomercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970410/
https://www.ncbi.nlm.nih.gov/pubmed/21577772
http://dx.doi.org/10.1107/S1600536809038732
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