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Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
The cyclohexane-1,3-dicarboxylate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxylate group in an equatorial position and the other in an axial position of the cyclohexane ring, which adopts a chair conformation. The carbo...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970416/ https://www.ncbi.nlm.nih.gov/pubmed/21577714 http://dx.doi.org/10.1107/S1600536809035168 |
Sumario: | The cyclohexane-1,3-dicarboxylate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxylate group in an equatorial position and the other in an axial position of the cyclohexane ring, which adopts a chair conformation. The carboxylate groups function as bridges to two adjacent Zn(II) atoms, generating a layer motif. Adjacent layers are linked through the 4,4′-bipyridine N-heterocycle, forming a three-dimensional network; the geometry of Zn(II) is square-pyramidal with the N atom of the N-heterocycle occupying the apical position. The N-heterocycle lies about a center of inversion and is disordered in a 1:1 ratio with respect to the C atoms bearing H atoms. |
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