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Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
The cyclohexane-1,3-dicarboxylate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxylate group in an equatorial position and the other in an axial position of the cyclohexane ring, which adopts a chair conformation. The carbo...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970416/ https://www.ncbi.nlm.nih.gov/pubmed/21577714 http://dx.doi.org/10.1107/S1600536809035168 |
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author | Rizal, Mohd. Razali Ng, Seik Weng |
author_facet | Rizal, Mohd. Razali Ng, Seik Weng |
author_sort | Rizal, Mohd. Razali |
collection | PubMed |
description | The cyclohexane-1,3-dicarboxylate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxylate group in an equatorial position and the other in an axial position of the cyclohexane ring, which adopts a chair conformation. The carboxylate groups function as bridges to two adjacent Zn(II) atoms, generating a layer motif. Adjacent layers are linked through the 4,4′-bipyridine N-heterocycle, forming a three-dimensional network; the geometry of Zn(II) is square-pyramidal with the N atom of the N-heterocycle occupying the apical position. The N-heterocycle lies about a center of inversion and is disordered in a 1:1 ratio with respect to the C atoms bearing H atoms. |
format | Text |
id | pubmed-2970416 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29704162010-12-30 Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4) O:O′:O′′:O′′′)dizinc(II)] Rizal, Mohd. Razali Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The cyclohexane-1,3-dicarboxylate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxylate group in an equatorial position and the other in an axial position of the cyclohexane ring, which adopts a chair conformation. The carboxylate groups function as bridges to two adjacent Zn(II) atoms, generating a layer motif. Adjacent layers are linked through the 4,4′-bipyridine N-heterocycle, forming a three-dimensional network; the geometry of Zn(II) is square-pyramidal with the N atom of the N-heterocycle occupying the apical position. The N-heterocycle lies about a center of inversion and is disordered in a 1:1 ratio with respect to the C atoms bearing H atoms. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970416/ /pubmed/21577714 http://dx.doi.org/10.1107/S1600536809035168 Text en © Rizal and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rizal, Mohd. Razali Ng, Seik Weng Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4) O:O′:O′′:O′′′)dizinc(II)] |
title | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4)
O:O′:O′′:O′′′)dizinc(II)] |
title_full | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4)
O:O′:O′′:O′′′)dizinc(II)] |
title_fullStr | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4)
O:O′:O′′:O′′′)dizinc(II)] |
title_full_unstemmed | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4)
O:O′:O′′:O′′′)dizinc(II)] |
title_short | Poly[(μ(2)-4,4′-bipyridine-κ(2)
N:N′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4)
O:O′:O′′:O′′′)dizinc(II)] |
title_sort | poly[(μ(2)-4,4′-bipyridine-κ(2)
n:n′)bis(μ(4)-cyclohexane-1,3-dicarboxylato-κ(4)
o:o′:o′′:o′′′)dizinc(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970416/ https://www.ncbi.nlm.nih.gov/pubmed/21577714 http://dx.doi.org/10.1107/S1600536809035168 |
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