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Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)]

The cyclo­hexane-1,3-dicarboxyl­ate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxyl­ate group in an equatorial position and the other in an axial position of the cyclo­hexane ring, which adopts a chair conformation. The carbo...

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Detalles Bibliográficos
Autores principales: Rizal, Mohd. Razali, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970416/
https://www.ncbi.nlm.nih.gov/pubmed/21577714
http://dx.doi.org/10.1107/S1600536809035168
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author Rizal, Mohd. Razali
Ng, Seik Weng
author_facet Rizal, Mohd. Razali
Ng, Seik Weng
author_sort Rizal, Mohd. Razali
collection PubMed
description The cyclo­hexane-1,3-dicarboxyl­ate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxyl­ate group in an equatorial position and the other in an axial position of the cyclo­hexane ring, which adopts a chair conformation. The carboxyl­ate groups function as bridges to two adjacent Zn(II) atoms, generating a layer motif. Adjacent layers are linked through the 4,4′-bipyridine N-heterocycle, forming a three-dimensional network; the geometry of Zn(II) is square-pyramidal with the N atom of the N-heterocycle occupying the apical position. The N-heterocycle lies about a center of inversion and is disordered in a 1:1 ratio with respect to the C atoms bearing H atoms.
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spelling pubmed-29704162010-12-30 Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)] Rizal, Mohd. Razali Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The cyclo­hexane-1,3-dicarboxyl­ate dianion in the title three-dimensional coordination polymer, [Zn(2)(C(8)H(10)O(4))(2)(C(10)H(8)N(2))](n), has one carboxyl­ate group in an equatorial position and the other in an axial position of the cyclo­hexane ring, which adopts a chair conformation. The carboxyl­ate groups function as bridges to two adjacent Zn(II) atoms, generating a layer motif. Adjacent layers are linked through the 4,4′-bipyridine N-heterocycle, forming a three-dimensional network; the geometry of Zn(II) is square-pyramidal with the N atom of the N-heterocycle occupying the apical position. The N-heterocycle lies about a center of inversion and is disordered in a 1:1 ratio with respect to the C atoms bearing H atoms. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970416/ /pubmed/21577714 http://dx.doi.org/10.1107/S1600536809035168 Text en © Rizal and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rizal, Mohd. Razali
Ng, Seik Weng
Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
title Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
title_full Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
title_fullStr Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
title_full_unstemmed Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
title_short Poly[(μ(2)-4,4′-bipyridine-κ(2) N:N′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) O:O′:O′′:O′′′)dizinc(II)]
title_sort poly[(μ(2)-4,4′-bipyridine-κ(2) n:n′)bis­(μ(4)-cyclo­hexane-1,3-dicarboxyl­ato-κ(4) o:o′:o′′:o′′′)dizinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970416/
https://www.ncbi.nlm.nih.gov/pubmed/21577714
http://dx.doi.org/10.1107/S1600536809035168
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