(RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate

In the title compound, C(11)H(11)NO(3), a modified synthetic acetate derivative, the four memebered β-lactam ring is roughly planar, with a maximum deviation of 0.21 (3) Å, and makes a dihedral angle of 81.46 (14)° with the phenyl ring. In the crystal, a single N—H⋯O hydrogen bond links mol­ecules i...

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Detalles Bibliográficos
Autor principal: Li, Yangjun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970417/
https://www.ncbi.nlm.nih.gov/pubmed/21578026
http://dx.doi.org/10.1107/S1600536809038860
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author Li, Yangjun
author_facet Li, Yangjun
author_sort Li, Yangjun
collection PubMed
description In the title compound, C(11)H(11)NO(3), a modified synthetic acetate derivative, the four memebered β-lactam ring is roughly planar, with a maximum deviation of 0.21 (3) Å, and makes a dihedral angle of 81.46 (14)° with the phenyl ring. In the crystal, a single N—H⋯O hydrogen bond links mol­ecules into a chain parallel to the a axis and thus stabilizes the structure. Although the absolute configuration could not be reliably determined, the compound corresponds to the diasteroisomer (RS/SR)
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spelling pubmed-29704172010-12-30 (RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate Li, Yangjun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(11)NO(3), a modified synthetic acetate derivative, the four memebered β-lactam ring is roughly planar, with a maximum deviation of 0.21 (3) Å, and makes a dihedral angle of 81.46 (14)° with the phenyl ring. In the crystal, a single N—H⋯O hydrogen bond links mol­ecules into a chain parallel to the a axis and thus stabilizes the structure. Although the absolute configuration could not be reliably determined, the compound corresponds to the diasteroisomer (RS/SR) International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970417/ /pubmed/21578026 http://dx.doi.org/10.1107/S1600536809038860 Text en © Yangjun Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Yangjun
(RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate
title (RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate
title_full (RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate
title_fullStr (RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate
title_full_unstemmed (RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate
title_short (RS/SR)-2-Oxo-4-phenyl­azetidin-3-yl acetate
title_sort (rs/sr)-2-oxo-4-phenyl­azetidin-3-yl acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970417/
https://www.ncbi.nlm.nih.gov/pubmed/21578026
http://dx.doi.org/10.1107/S1600536809038860
work_keys_str_mv AT liyangjun rssr2oxo4phenylazetidin3ylacetate

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